The excited-state proton transfer and subsequent intramolecular ion pair formation of a cupreidine-derived Cinchona organocatalyst (BnCPD) were studied in THF-water mixtures using picosecond time-resolved fluorescence together with global analysis. Full spectral and kinetic characterization of all the fluorescent species allowed us to monitor the 3-step process for the ion pair dissociation. In...

the computer simulation program of a practical scale reverse electrodialysis process has been developed based on the program for saline water electrodialysis. the program is applied to compute the performance of an industrial-scale reverse electrodialysis stack (effective membrane area s = 1 m × 1 m = 1 m2, cell pair number n = 300 pairs). the stack operatingconditions are optimized. seawater a...

The present work reported density, viscosity, speed of sound, electrical conductivity and refractive index data of L-alanine in the aqueous solutions of 1-hexyl-3-methylimidazolium ibuprofenate at T= 298.15 K. Using the measured data, partial molar volume of transfer ( ), partial molar isentropic compressibility of transfer ( ), viscosity B-coefficient of transfer (∆traB), ion association const...

Abstract The formation of dust ion-acoustic shocks (DIASs) in a four-component quantum plasma whose constituents are electrons, both positive and negative ions and immobile charged dust grains, is studied. The effects of both the dissipation due to kinematic viscosity and the dispersion caused by the charge separation as well as the quantum tunneling due to the Bohm potential are taken into acc...

Room-temperature ionic liquids exert vanishingly small vapor pressures under ambient conditions. Under reduced pressure, certain ionic liquids have demonstrated volatility, and they are thought to vaporize as intact cation-anion ion pairs. However, ion pair vapors are difficult to detect because their concentration is extremely low under these conditions. In this Letter, we report the products ...