Subnanometer-resolved local electron energy structure was measured in PbS quantum dot superlattice arrays using valence electron energy loss spectroscopy with scanning transmission electron microscopy. We found smaller values of the lowest available transition energies and an increased density of electronic states in the space between quantum dots with shorter interparticle spacing, indicating ...

Subtle features of the reaction front formation in the A+B-->0 reaction are reported for the initially random and equal A+B reactant distribution. Three nonclassical parameters (initial linewidth, minimum, and maximum), for each interparticle gap and nearest neighbor distance distributions, are derived, as a function of time, using Monte Carlo simulations. These empirical front measures and the...

Secondary nucleation, in the absence of attrition, is known to be dependent on external fields, such as contact forces, shear, or interparticle forces. In this contribution, thermodynamic effect presence seed crystal surface secondary nucleation derived context classical theory. The Gibbs free energy for formation a cluster close calculated with addition energies, namely, van der Waals attracti...

A method is presented to control the in-plane ordering, size, and interparticle distance of nanoparticles fabricated by evaporation through a mask of colloidal particles. The use of optical tweezers combined with critical point drying gives single-particle position control over the colloidal particles in the mask. This extends the geometry of the colloidal masks from (self-organized) hexagonal ...

Maghemite (γ-Fe2O3) nanoparticles (NPs) can be successfully dispersed in a protic ionic liquid, ethylammonium nitrate (EAN), by transfer from aqueous dispersions into EAN. As the aqueous systems are well controlled, several parameters can be tuned. Their crucial role towards the interparticle potential and the structure of the dispersions is evidenced: (i) the size of the NPs tunes the interpar...

The size of gold nanoparticle aggregates was controlled by manipulating the interparticle interaction. To manipulate the interparticle interaction of gold nanoparticles prepared by citrate reduction, we applied the substitutive adsorption of benzyl mercaptan on the particle surface in the absence of the cross-linking effect. Various experimental techniques such as UV-vis absorption spectroscopy...

Self-assembly of nanoparticles (NPs) into tailored structures is a promising strategy for the production and design of materials with new functions. In this work, 2D arrays of iron oxide NPs with interparticle distances tuned by grafting fatty acids and dendritic molecules at the NPs surface have been obtained over large areas with high density using the Langmuir-Blodgett technique. The anchori...

The most important microstructural processes involved in shock consolidation are identified and illustrated for a nickel-based superalloy and silicon carbide. Interparticle melting, vorticity, voids, and particle fracture are observed. Various energy dissipation processes are identified and analyzed: plastic deformation, interparticle friction, microkmetic energy, defect generation. An analytic...