Glucose, maltodextrin, and sucrose exhibit significant differences in their alkaline reaction properties and interactions in aluminate/silicate cement slurries that result in diverse hydration behaviors of cements. Using 1D solution- and solid-state (13)C nuclear magnetic resonance (NMR), the structures of these closely related saccharides are identified in aqueous cement slurry solutions and a...

The relationship between composition, structure, and resistance to fracture remains poorly understood. Here, based on molecular dynamics simulations, we report that 1 sodium silicate glasses (NS) and calcium–silicate–hydrates (CSH) feature an anomalous maximum in fracture toughness. In the framework of topological constraint theory, this anomaly is correlated to a flexible-to-rigid transition, ...

–Flyash based geopolymer concrete is introduced in 1979 by Davidovits to reduce the use of OPC in concrete. Geopolymer is an inorganic alumino-hydroxide polymer synthesized form predominantly silicon and aluminum materials of geological origin and by product materials such as flyash (with low calcium). In this paper an attempt is made to study strength properties of geopolymer concrete using lo...

The structure of a novel molecularly ordered two-dimensional (2D) silicate framework in a surfactant-templated mesophase has been established by using a combination of solid-state nuclear magnetic resonance (NMR) spectroscopy, X-ray diffraction, and quantum chemical and empirical force-field modeling. These materials are unusual in their combination of headgroup-directed 2D crystalline framewor...

Although inorganic crystalline phosphors can exhibit high quantum efficiency, their use in phosphor films has been limited by a reliance on organic binders that have poor durability when exposed to high-power and/or high excitation energy light sources. To address this problem, Sn(2+)-doped transparent phosphate films measuring several micrometers in thickness have been successfully prepared th...

binders are of prime importance in the agglomeration of iron ore concentrates. in this research, strength and density of briquette produced from the magnetite concentrate of gol-e-gohar were investigated using different binders at various applied pressures. the results showed that peridor was the most effective binder relative to bentonite and lime. for all types of binders, the increase in bin...

Microstructural and mechanical properties of alkali activated binders based on blends of Colombian granulated blast furnace slag (GBFS) and fly ash (FA) were investigated. The synthesis of alkali activated binders was conducted at 85 °C for 24 h with different slag/fly ash ratios (100:0, 80:20, 60:40, 40:60, 20:80, and 0:100). Mineralogical and microstructural characterization was carried out b...