The reaction of iron (II) with 2, 6-diacetylprydine dioxime (H2dapd) and 2-acetylprydine monoxime (Hapm) in 10% and 60% v/v ethanol-water solution at pH 2.5 and 7.5, respectively, were studied using direct and first derivative spectrophotometry. Fe (III) is reduced by H2dapd and gives iron (II) complex. A simple, rapid, selective and sensitive method for the determination of Fe (II), Fe (III) a...

Kinetics studies provide mechanistic insight regarding the formation of dinitrosyl iron complexes (DNICs) now viewed as playing important roles in the mammalian chemical biology of the ubiquitous bioregulator nitric oxide (NO). Reactions in deaerated aqueous solutions containing FeSO4, cysteine (CysSH), and NO demonstrate that both the rates and the outcomes are markedly pH dependent. The dinuc...

in parts of desert regions in our country, groundwater is the only source of fresh water and due to geological formation, the concentration of hexavalent chromium in groundwater will reach beyond the allowed limits. furthermore, previous studies showed that hexavalent chromium is a cancerous substance for humans and toxic for other organisms. in this study the removal of hexavalent chromium fro...

The feasibility of natural apatite for adsorptive removal of Fe from aqueous solution was investigated. Batch experiments were performed as function of process parameters such as contact time, initial concentration of Fe, temperature, apatite dosage and pH. The natural apatite exhibited a high performance for the removal of Fe from aqueous solution. The pH value clearly affects the removal mech...

background: despite the ever-increasing beneficial applications of magnetic nanoparticles in biological systems, few studies have been carried out on the combined effects of nanoparticles (fe and ni) on human health. in the present study the effects of fe2nio4 nanoparticle on inflammatory factors were assessed. methods : twenty-four wistar rats were randomly divided into 3 groups: two groups we...

Scalable energy conversion/storage by water splitting is significantly hindered the slow kinetics of oxygen evolution reaction (OER). Implementation electrochemical catalysts with low cost and high turn-over efficiency, or application a photoanode in photoelectrochemical (PEC) cell using semiconductor proper protection layer are two possible solutions. Herein, binary Iron-group alloy films (Ni-...

a new sensitive and selective spectrophotometric method for the determination of iron using a pvc membrane containing bathophenanthroline and dioctylphethalate as the solid phase extraction medium is investigated. fe(ii) in an aqueous sample solution is trapped on the membrane with an anion species, picrate ion and forms a complex with bathophenanthroline. the absorbance of the red-orange membr...

In this study, the plants of maize (Zea mays L.cv.ksc700) were grown in Hoagland solution containing 1, 3 and 5 mM KH2PO4 or K2HPO4 under controlled conditions. At similar levels of mono and diphosphate, plants supplied with monophosphate have produced higher content of dry matter and characterized with higher total chlorophyll content and longer and well proliferated root system than those tre...

Herein, the impact of chemical stability RedOx mediator ferricyanide, K3[Fe(CN)6] (FC), a type buffer solution used for bioreceptor preparation, gel composition (carboxymethylcellulose, CMC, Aerosile, AS, and alginate, ALG) on long term glucose test-strips their analytical performance was examined. By simple addition ALG to functional aiming improve its viscosity, we managed enhance sensitivity...

Cobalt sulfate was recovered from crushed and screened prismatic type spent lithium ion batteries (LIBs) containing 5~20 % Co, 5~7 % Li, 5~10 % Ni, 15% organic chemicals, and 7% plastics together with Cu, Al, Fe, and Mn. Cobalt was reductively leached from the -16 mesh fraction in 1 h by stirring with 2 M H2SO4 and 6 vol% H2O2, at 60 C and 300 rpm using a solid/liquid ratio of 100 g/L to give a...