Gaseous monochlorobenzene was irradiated with KrF excimer laser (248 nm) under reduced pressure. The photodecomposition was an apparent first order reaction. When the system contained no additive gas, the photolysis was found to give benzene (conversion yield: 49%) in the gas phase and many unidentified products in the solid phase. On the other hand, in the presence of oxygen, carbon dioxide (1...

the hydrolysis of sodium borohydride as a source of hydrogen gas is studied at different mole ratios of h+ to nabh4. the sulfonated porous carbon (spc) is used as a source of hydrogen ion and catalyst. it is found that the sulfonated porous carbon exhibits high activity for the hydrolysis of nabh4 to generate hydrogen gas at room temperature in comparison to amberlyst-15 and nafion-nr50. the ki...

In making the gas-solid-liquid phase analysis, based on the collaborative study of the internal and external humidification ratio of desulfurization efficiency, determine the humidifier ratio within 60% to 75%, that can make the best balance between the respective merits of a simple tower humidifiers tower humidifier way, optimizing the overall desulfurization reaction, effectively reducing the...

Our interest in the exchange reaction of oxygen between the gas phase and oxides is twofold: (i) to understand the mechanistic details of one of the "simplest" gas-solid reactions which nevertheless exhibits an astonishing complexity in terms of reaction pathways, (ii) to use this knowledge for improving electrochemical devices which rely critically on a fast oxygen incorporation rate such as c...

Well-crystallized Ba2SiO4:Eu powders were grown on a substrate by the vapor phase reaction between a mixed powder (barium carbonate and europium oxide) and SiO gas. The vaporization of SiO occurs at 1400–1600◦C from the SiO2 source (or SiO powder) in a reducing atmosphere. The formed SiO gas was transported by 95 vol% Ar 5 vol% H2 gas and reacted with the raw material powders. The emission inte...

The mechanism, synthetic application, scaling, and industrial production with gas-solid and solid-solid reactions without producing wastes is outlined. These reactions profit from lowered activation energy (with respect to melt reactions), favorable kinetics with definite end of reaction, and mostly reaction specificity giving only one product in pure form without workup necessity. They proceed...

This paper describes a laboratory-scale study on the use of recirculating cyclones as reaction chambers for dry scrubbing of gaseous HCl with solid slaked lime particles. This gas cleaning system combines a numerically optimized reverse flow gas cyclone (RS_VHE geometry) with a straight-through cyclone concentrator, which simultaneously increases the capture of the solid particles and promotes ...

background and objectives: analytical methods for volatile organic compounds (vocs) in different samples need extraction of compounds, by applying hazardous solvents. solid phase micro-extraction (spme) is a solvent-free equilibrium extraction method, in which proper calibration can allow quantitative determinations of vocs at a very good sensitivity without the use of any organic solvent. vocs...

background: determination of organic pollutants usually requires extraction of the pollutants from samples, using hazard­ous solvent. solid phase micro-extraction (spme) is a solvent-free equilibrium extraction method, in which, proper calibra­tion can allow quantitative measurements of organic pollutants at a very good sensitivity without the use of any organic sol­vent. because individual voc...