In a preceding paper (Brouwers and Chesters, Int. J. Heal Mass Transfer 35, l-11 (1992)) possible supersaturation in a film and in the bulk of a binary mixture has been discussed. In the present analysis the exact conditions for fog formation and the magnitude of the fogging and superheated regions in the film are first determined. Next, the governing equation of diffusion and energy (coupled w...

Adaptive speckle imaging interferometry (ASII): New technology for advanced drying analysis of coatings In this work a new optical technology, ASII, is presented, for the study of film formation from all kinds of dispersed systems, such as latexes, emulsions or solvent-borne suspensions. Various film-forming products have been investigated, including water-borne coatings, on various types of su...

A system for the simultaneous measurement of small-angle X-ray scattering and wide-angle X-ray diffraction (SAXS–WAXD) and the thickness of a coating film, obtained with an automatic coater, during film formation has been developed. The system was installed on beamline BL03XU at SPring-8. As model specimens, poly(methyl methacrylate)-b-poly(n-butyl acrylate)-b-poly(methyl methacrylate) (PMMA-b-...

A mechanism for the formation of quantum dots on the surface of thin solid films is proposed, not associated with the Asaro-Tiller-Grinfeld instability caused by epitaxial stresses. This mechanism, free of stress, involves instability of the film surface due to strong anisotropy of the surface energy of the film, coupled to wetting interactions between the film and the substrate. According to t...

The interplay of hydrological, chemical and microbial processes in the formation of iron-rich floating films in aquatic environments at a circumneutral pH The direct contribution of microbial activity to the formation of iron-oxide minerals is difficult to prove in wetlands due to the high reactivity of solid iron phases with different compounds and the variety of redox processes that may occur...

This study focuses on the semiconductor properties of passive films formed on AISI 420 stainless steel immersed in four nitric acid solutions under open circuit potential (OCP) conditions. For this purpose, the passivation parameters and semiconductor properties of passive films were derived from potentiodynamic polarization and Mott–Schottky analysis, respectively. The OCP plots showed that th...

We report an experimental investigation on the effect of mutual diffusion in polymeric systems on film drainage between two captive drops. The main objective is to study the influence of diffuse interfaces on film drainage. This is done by using material combinations with different interfacial properties and interferometric visualization of the film between two interacting drops. For highly dif...

in this paper, the electrochemical behaviour of passive films formed on aisi 321 stainless steel (aisi 321)immersed in 0.1 m naoh + 0.1 m koh solution was evaluated by different electrochemical techniques. forthis purpose, passive films were formed at open circuit potential for 1 to 12 hours and then electrochemicalmeasurements were done. the polarization curves suggested that aisi 321 showed e...

Zinc dialkyldithiophosphate additives are used to control wear and inhibit oxidation in almost all engine oils as well as many other types of lubricant. They limit wear primarily by forming a thick, protective, phosphate glass-based tribofilm on rubbing surfaces. This film formation can occur at low temperatures and is relatively indifferent to the chemical nature of the substrate. There has be...

We analyze the coherent-structure interaction and the formation of bound states in active dispersive-dissipative nonlinear media using a viscous film coating a vertical fiber as a prototype. The coherent structures in this case are droplike pulses that dominate the evolution of the film. We study experimentally the interaction dynamics and show evidence for formation of bound states. A theoreti...