نتایج جستجو برای: ferrocene carboxylic acid
تعداد نتایج: 752471 فیلتر نتایج به سال:
Reaction of aryl methyl ketone with isatin in the presence of a base afforded 2- arylquinoline-4-carboxylic acid (3). Reaction of diazomethane with compound 3 yielded the ester 4. Compound 5 was prepared from the reaction of N, N'-dialkylethyl (or propyl) arnine with 4. Addition of hydrazine hydrate to compound 4a gave 2- (2- pyridyl) quinoline-4-carboxylic acid hydrazide (6). Reaction of l...
reaction of aryl methyl ketone with isatin in the presence of a base afforded 2- arylquinoline-4-carboxylic acid (3). reaction of diazomethane with compound 3 yielded the ester 4. compound 5 was prepared from the reaction of n, n'-dialkylethyl (or propyl) arnine with 4. addition of hydrazine hydrate to compound 4a gave 2- (2- pyridyl) quinoline-4-carboxylic acid hydrazide (6). reaction of ...
Carboxylic acid derivatives are the most widely occurring of all molecules, both in laboratory chemistry and in biological pathways. Specifically, acid derivatives are compounds in which the hydroxyl group of the carboxylic acid has been replaced by another acyl substituent that can act as a leaving group in nucleophilic acyl substitutions. These compounds can be acid halides, acid anhydrides, ...
the treatment equimolar quantities of carboxylic acids with acid chlorides in the presence of zno brings abouthighly efficient unsymmetrical anhydrides at room temperature in solvent-free condition. reactivity trendsfavored formation of the product using both electron deficient and rich aryl acids and acid chlorides.
Ferrocene derivatives are amongst the most promising electroactive organic electrolytes. The bottleneck problems of their application in aqueous redox flow batteries poor solubility and lower potential as well complexity modification methods to solve these problems. In this study, a benzenesulfonic acid group is easily introduced into ferrocene structure by mature diazotization reaction, synthe...
Some derivatives of biphenyl-4-carboxylic acid 2-(aryl)-4-oxo-thiazolidin-3-yl –amide were synthesized and studied for their antimicrobial activity. These compounds were prepared from biphenyl-4-carboxylic-acid hydrazides. Biphenyl-4-carboxylic-acid hydrazides 1 on refluxing with aryl aldehydes in the presence of catalytic amount of glacial acetic acid furnish the biphenyl-4-carboxylic acid hyd...
The facile side-specific insertion, on the solid phase, of one or two ferrocene moieties into peptide nucleic acid (PNA) oligomers by click chemistry is presented.
Alkylation of pyrazine-2-carboxylic acid and 6-chloropyrazine-2-carboxylic acid with radicals generated by silver nitrate-catalyzed oxidative decarboxylation of pivalic acid afforded 5-(1,1dimethylethyl)pyrazine-2-carboxylic acid and 6-chloro-5-(l,l-dimethylethyl)pyrazine-2-carboxylic acid. Condensation of chlorides of the latter three halogenated and/or alkylated pyrazine-2carboxylic acids wit...
approved: T. Mark Zabriskie L-pipecolic acid (L-PA), a six carbon imino acid, is an intermediate of lysine degradation in various organisms including bacteria, yeast, fungi and mammals. In primates, the oxidation of L-PA by the enzyme L-pipecolate oxidase (L-PO) is the rate determining step of L-lysine degradation in the central nervous system. This thesis describes efforts to probe the L-PO me...
Two molecules of indole derivative, e.g. indole-5-carboxylic acid, reacted with one molecule of thiol, e.g. 1,2-ethanedithiol, in the presence of trifluoroacetic acid to yield adducts such as 3-[2-(2-amino-5-carboxyphenyl)-1-(2-mercaptoethylthio)ethyl]-1Hindole-5-carboxylic acid. Parallel formation of dimers, such as 2,3-dihydro-1H,1'H-2,3'-biindole-5,5'-dicarboxylic acid and trimers, such as 3...
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