Iron incorporated zeolites were prepared from Na-A type zeolite synthesized from melting slag and FeCl3 solution and applied as adsorbents for NH3 and H2S gases. Iron incorporated zeolite was pelletized, calcined and used for gas adsorption experiment. XRD analyses of the zeolite revealed that Fe3þ concentration of solution more than 90mM could destruct the zeolite network structure. It was obs...

Environmental concern associated with safe handling disposal of corrosive mineral acids such as HF have encouraged the development of safer and non waste producing alternative for application in catalysis. In this sense ,mesoporous materials attracted much attention of catalysis to transform big molecules into its useful products. In the present study we have synthesized, mesoporous Fe-MCM-41an...

Catalytic behavior of isomorphously substituted B-, Al-, Ga-, and Fe-containing extra-large pore UTL zeolites was investigated in Knoevenagel condensation involving aldehydes, Pechmann condensation of 1-naphthol with ethylacetoacetate, and Prins reaction of β-pinene with formaldehyde and compared with large-pore aluminosilicate zeolite beta and representative Metal-Organic-Frameworks Cu3(BTC)2 ...

This study explored the possibility of recovering waste powder from photonic industry into two useful resources, sodium fluoride (NaF) and the silica precursor solution. An alkali fusion process was utilized to effectively separate silicate supernatant and the sediment. The obtained sediment contains purified NaF (>90%), which provides further reuse possibility since NaF is widely applied in ch...

The acid properties of mesostructured aluminosilicates synthesized from gels precursors of colloidal ZSM-5 zeolite have been studied by FTIR spectroscopy of basic probe molecules (ammonia, CO and propene). It is shown that these materials possess stronger acid sites with higher thermal stability than those of conventional Al-MCM-41. These results explain the enhaced m-xylene isomerization activ...