نتایج جستجو برای: extended debye hückel model
تعداد نتایج: 2269226 فیلتر نتایج به سال:
A simple analytical approach to estimate thermodynamic properties of model Yukawa systems is presented. The approach extends the traditional Debye-Hückel theory into the regime of moderate coupling and is able to qualitatively reproduce thermodynamics of Yukawa systems up to the fluid-solid phase transition. The simplistic equation of state (pressure equation) is derived and applied to the hydr...
An analysis is given of several biologically important processes, connected with the crystallization and kinetics of liophilization in aqueous physiological solutions. These are glass formation and vitrification of life, precipitation of slightly soluble salts and kinetics of crystallization in human urine, and the solution of CaOX concretions under the influence of biocompatible solubilizators...
We study the global existence and space-time asymptotics of solutions for a class of nonlocal parabolic semilinear equations. Our models include the Nernst–Planck and the Debye–Hückel drift-diffusion systems as well as parabolic-elliptic systems of chemotaxis. In the case of a model of self-gravitating particles, we also give a result on the finite time blow up of solutions with localized and o...
We study the global existence and space-time asymptotics of solutions for a class of nonlocal parabolic semilinear equations. Our models include the Nernst–Planck and the Debye–Hückel drift-diffusion systems as well as parabolic-elliptic systems of chemotaxis. In the case of a model of self-gravitating particles, we also give a result on the finite time blow up of solutions with localized and o...
The Debye–Hückel Limiting Law (DHLL) correctly predicts the thermodynamic behavior of dilute electrolyte solutions. Most articles and books explain this law using Peter Debye Erich Hückel’s original formalism linearizing Poisson–Boltzmann equation for a simple model. Brilliant in its own right, approach does not fully which microstates contribute range theory. Notably, establish Energy Multipli...
Abstract. We study the electrostatic Casimir effect and related phenomena in equilibrium statistical mechanics of classical (non-quantum) charged fluids. The prototype model consists of two identical dielectric slabs in empty space (the pure Casimir effect) or in the presence of an electrolyte between the slabs. In the latter case, it is generally believed that the long-ranged Casimir force due...
This paper presents a simple and efficient equation of state which can be used for quick and accurate computing of the thermodynamic functions of partly ionized and weakly coupled plasmas. Based on the free energy minimization method, the improvement of the equation of state includes a detailed account of the physical processes of non-ideal effects consisting of electron degeneracy, Coulomb cou...
Abstract. We study the electrostatic Casimir effect and related phenomena in equilibrium statistical mechanics of classical (non-quantum) charged fluids. The prototype model consists of two identical dielectric slabs in empty space (the pure Casimir effect) or in the presence of an electrolyte between the slabs. In the latter case, it is generally believed that the long-ranged Casimir force due...
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