A green method for the synthesis of high-performance diketopyrrolopyrrole pigments using diethyl succinate in the presence of mixture of ionic liquids is reported. Although, alkaline condition is needed in the succinate ester route for synthesis of the pigments, in the present study, the replacement possibility of conventional organic base by mixture of BMIMOH and BMIMBF4 ionic liquids was inve...

The purpose of this research is the synthesis alkyl esters from CPO through transesterification reaction using catalyst CaO-MgO. This experimental laboratory stages: (1) refinement, (2) determination free fatty acid numbers, (3) activation CaO-MgO catalysts, (5) with alcohol (methanol and ethanol), (6) identification components synthesized ester GC-MS,characterization including density, viscosi...

We report on the synthesis of a series poly(ester-anhydride) composed following dicarboxylic acids: adipic, suberic, sebacic, dodecanedioic acids; and hydroxyalkanoic ricinoleic 12-hydroxystearic acid with control molecular weight approaching from new method in which well-defined ester monomers are first synthesized by stepwise addition acids molecules into melted acids. The key advantage this ...

Oligonucleotides bearing a terminal lipophilic group attached through a biodegradable ester bond should be useful as antisense pro-drugs with improved cellular uptake. The synthesis of 5'-ester oligonucleotides is, however, problematic due to lability of the ester bond during aqueous ammonia treatment that is commonly used for the deprotection of synthetic oligonucleotides. The synthesis of 5'-...

Chemo-enzymatic synthesis of ester-linked 2-phenylindole-3-carboxaldehyde-glucose conjugate (2-phenylindole-3-carboxyl-10″-O-β-D-glucosyl ester) was achieved by using plant cell cultures as biocatalysts. The anticancer agent, 2-phenylindole-3-carboxaldehyde, induced apoptosis in cells, whereas 2-phenylindole-3-carboxyl-10″-O-β-D-glucosyl ester showed no cytotoxicity and induced no apoptosis.

transesterification, one of the most effective methods for ester synthesis, is usually conducted under acid or basicconditions. although quite a few methods have been reported for transesterification, they are not general as far asp-ketoesters are concerned. some of these methods used toxic, expensive reagents and in relatives large amount. inthis research, transesterification reaction six type...

A simple procedure for the one-pot synthesis of 2,5-furandicarboxylic acid dimethyl ester (FDME) from galactaric (mucic) via carbonate (DMC) chemistry is presented. The compound was isolated as a white powder in 70% yield.

An efficient de novo synthesis of vineomycinone B2 methyl ester has been achieved. The longest linear route required only 14 steps from achiral commercially available starting materials (4.0% overall yield). The key transformations included the de novo asymmetric synthesis of two key fragments, which were joined by a convergent late stage Suzuki's glycosylation for the construction of the aryl ...

Thermoplastic elastomers based on polyesters/carbonates have the potential to maximize recyclability, degradability and renewable resource use. However, they often underperform suffer from familiar trade-off between strength extensibility. Herein, we report well-defined reprocessable poly(ester-b-carbonate-b-ester) with impressive tensile strengths (60 MPa), elasticity (>800 %) recovery (95 %)....