High-performance polymers are an important class of materials that used in challenging conditions, such as aerospace applications. Until now, 3D printing based on stereolithography processes can not be performed due to a lack suitable materials. There is report new and compositions enable objects having extremely high thermal resistance, with Tg 283 °C excellent mechanical properties. The by lo...

In response to present and future fossil resource depletion, chemicals production from an alternate raw materials base must be considered. The biologically catalysed degradation of photos:ynthetically stored energy, such as starch and ligno-cellulosics, is an important approach for chemicals production. The objective of this study is to increase the productivity of acrylate from propionate, usi...

In this work, eleven heteroleptic copper complexes were designed and studied as photoinitiators of polymerization in three-component photoinitiating systems combination with an iodonium salt amine. Notably, ten them exhibited panchromatic behavior could be used for long wavelengths. Ferrocene-free capable efficiently initiating both the radical cationic polymerizations similar performances to t...

In this work, six new fluorescent dyes derived from the naphthalimide scaffold (Napht1–Napht6) were synthesized and used as high-performance photoinitiating systems (PISs) in two three-component (combined with iodonium salt (Iod) and/or an electron donor amine (such N-phenylglycine[NPG])) for radical photopolymerization of acrylate methacrylate monomers under visible light using a light-emittin...

An extension of the transferable potentials for phase equilibria-united atom (TraPPE-UA) force field to acrylate and methacrylate monomers is presented. New parameters were fit to the liquid density, normal boiling point, saturated vapor pressure, and (where experimentally available) critical constants of 1,3-butadiene, isoprene, methyl acrylate, and methyl methacrylate using Gibbs ensemble Mon...

Acrylamide, a neurotoxin and suspected carcinogen, is produced by industrial processes and during the heating of foods. In this study, the microbial diversity of acrylamide metabolism has been expanded through the isolation and characterization of a new strain of Rhodopseudomonas palustris capable of growth with acrylamide under photoheterotrophic conditions. The newly isolated strain grew rapi...