Despite a wealth of studies exemplifying the utility of the 2-5 keV X-ray range in speciation and electronic structure elucidation, the exploitation of this energy regime for the study of photochemical processes has not been forthcoming. Herein, a new endstation set-up for in situ photochemical soft X-ray spectroscopy in the 2-5 keV energy region at the Stanford Synchrotron Radiation Lightsourc...

a general overview on the prospective of various oxidation and combined processes in the treatment of tannery industry effluent are reported. various oxidation and combined processes such as uv/h2o2/hypochlorites, fenton and electro-oxidation, photo-chemical, photo-catalytic, electro-catalytic oxidation, wet air oxidation, ozonation, biological followed by ozone/uv/ h2o2, coagulation or ele...

The photochemical release of inorganic nitrogen from dissolved organic matter is an important source of bio-available nitrogen (N) in N-limited aquatic ecosystems. We conducted photochemical experiments and used mathematical models based on pseudo-first-order reaction kinetics to quantify the photochemical transformations of individual N species and their seasonal effects on N cycling in a moun...

salinity is one of major stresses which can severely limit plant production, especially in the arid and semi-arid regions. the present study was carried out to evaluate the impact of salinity stress on some physio-biochemical parameters in nitre bush plants (nitraria schoberi). thus, an experiment was carried out under natural conditions and salinity stress was induced by a combination of diffe...

We propose a rate process model for describing photochemical damage to retinal cells by short wavelength laser exposures. The rate equation for photochemical damage contains a positive rate that is temperature independent, and a negative (quenching) rate that is temperature dependent. Using the traditional Arrhenius integral to describe thermal damage, we derive damage threshold doses for both ...

groundwater makes up an important part of global freshwater resources, though it is often threatened by overuse of natural resources along with abundant production of wastes in modern society. this study aims to investigate the removal of three heavy metals including nickel, cadmium, and lead from groundwater via electrocoagulation, a suitable method for treatment of water-soluble compounds, de...

The resource intensive human activities (such as mining and extraction of mineral oils for betterment of life and modernization of society) have increased environmental pollution several folds. Products of mining and petrochemical industries are advantageous for the modern society. But waste generated such as BTEX from such industries are carcinogenic, toxic and causes adverse effects on enviro...

The Sydney basin region experiences some high ozone episodes in summer, especially in the north west and south west of Sydney. Observation-based methods can be used to provide a means to access the potential extent of photochemical smog problem at various regions in the Sydney area. In this study, the observation-based Integrated Empirical Rates (IER) model is used to determine and understand t...

A model-based approach is here developed and applied to predict the long-term trends of indirect photochemical processes in the surface layer (5m water depth) of Lake Maggiore, NW Italy. For this lake, time series of the main parameters of photochemical importance that cover almost two decades are available. As a way to assess the relevant photochemical reactions, the modelled steady-state conc...

The dual nature of ~3-~2-~4-~N,N-diethylamino!phenyl!ethenyl!-5,5-dimethyl-1,2-cyclohexenylidene!propanedinitrile ~Lemke-e! allows us to write both quasipermanent and erasable holographic gratings in the same storage volume. In the presence of a triplet excited sensitizer, Lemke-e undergoes a photochemical reaction allowing the creation of quasipermanent photochemical holographic gratings. In a...