a simple, rapid and efficient dispersive liquid–liquid microextraction by use of ionic liquid (il-dllme)method, followed by flame atomic absorption spectrometry (faas) was developed for the preconcentrationand determination of palladium in water samples. in this method, an appropriate mixture of acetone and octylmethyl imidazolium hexafluorophosphate was injected rapidly into the aqueous sample...

This application presents a fast, easy, and cost-effective method for the determination of 24 pesticide residues in red wine. Sample preparation involves the extraction of pesticides from red wine using the QuEChERS extraction method (AOAC version). The samples then undergo cleanup by dispersive solid-phase extraction (dSPE) using primary secondary amine (PSA) sorbent, which effectively retains...

In this study, a novel and simple dual-phase solvent system for the improvement of extraction capability of magnetic molecularly imprinted polymer (MIP) beads in aqueous sample was proposed. The method integrated MIP extraction and micro-liquid-liquid extraction (micro-LLE) into only one step. A magnetic MIP beads using atrazine as template was synthesized, and was applied to aqueous media by a...

Abstract In this study, magnetic-dispersive solid-phase extraction coupled with ion pair-dispersive liquid–liquid micro-extraction (MSPE-i-DLLME) was used to the pre-concentration and of five sulfonamides residues (sulfadiazine, sulfathiazole, sulfacetamide, sulfamethazine sulfamethoxazole) in animal foodstuffs. The are extracted using magnetic carbon nanocomposite then eluted acetonitrile. DLL...

objective(s):the present study reports the development and validation of a sensitive and rapid extraction method beside high performance liquid chromatographic method for the determination of crocetin in human serum. materials and methods:the hplc method was carried out by using a c18 reversed-phase column and a mobile phase composed of methanol/water/acetic acid (85:14.5:0.5 v/v/v) at the flow...

in this study, for the analysis of human urine samples, a novel method explained for the determination of celecoxib, a nonsteroidal anti-inflammatory drug (nsaid), using molecularly imprinted solid-phase extraction (mispe) coupled with high-performance liquid chromatography (hplc). the synthesis of the mip was performed by precipitation polymerization in methacrylic acid (maa), ethylene glycol ...

A new method of dispersive liquid-liquid microextraction (DLLME) combined with UV-Vis spectrophotometry was proposed for the determination of trace nickel using 2,2'-Furildioxime as chelating and spectrophotometric reagent. In the proposed approach chloroform and ethanol were used as extraction and dispersive solvents, respectively. Some factors influencing the extraction efficiency of nickel a...

Background and Objectives: Furfural (F) and hydroxymethyl furfural (HMF) are cyclic aldehydes, which are formed during the heat processing of foods. These chemical contaminants have received much attention due to their suspected health hazards and heat damage indicators. The aim of the present study was extraction and determination of F and HMF in baby-foods using dispersive liquid-liquid micro...

In this study a new method of preconcentration, separation and efficient measuring of so-called hollow fiber solid / liquid phase microextraction has been introduced for the determination of trace amounts of lorazepam (LRZ) in water samples, urine and hair using differential pulse voltammetry. To this end, a hybrid adsorbent material was used that involved ionic liquid assisted magnetic multi-w...