In the title compound, C(15)H(11)FO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The 2-phenyl ring is rotated out of the benzofuran plane, making a dihedral angle of 32.1 (2)°. The crystal structure is stabilized by aromatic π-π inter-actions between the benzene rings of neighbouring mol-ecules [centroid-c...

In the title compound, C(14)H(15)FO(4)S, the O atom and the methyl group of the methyl-sulfinyl substituent are located on opposite sides of the plane of the benzofuran fragment which is essentially planar with a mean deviation of 0.008 (1) Å from its least-squares plane. The crystal structure stabilized by three different inter-molecular non-classical C-H⋯O hydrogen bonds. The crystal structur...

In the title compound, C(13)H(13)FO(4)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The crystal structure exhibits four inter-molecular non-classical C-H⋯O hydrogen bonds. In addition, the crystal structure contains aromatic π-π inter-actions between the furan and benzene rings of adjacent mol-ecules [ce...

The alkoxycarbonylation of trimethylsilylacetylene has been studied in order to develop an atom economic sustainable synthesis 2‐(trimethylsilyl)acrylates, a family valuable intermediates. Pd(OAc) 2 combination with CH 3 SO H and diphenyl‐(pyridin‐2‐yl)phosphine or diphenyl‐(6‐methyl‐pyridin‐2‐yl)phosphine is active catalyst for the reaction affording mixtures sought 2‐(trimethylsilyl)acrylate ...

Isomerization, Reactivity, and Structural study of a Thioperoxide-bridged Dimolybdenum(V) Dimer Chi Minh Tuong April 8, 2004 The synthesis of the methyl thioperoxide-bridged dimolybdenum(V) dimer, structurally characterized by crystallography. The compound proved to be very stable to light and heat. The possibility of photolytic or thermolytic rearrangement of the methyl thioperoxide ligand (u-...

The title compound, C(28)H(30)N(4)O(2), synthesized from 4-[1-(4-ethoxy-phen-yl)-5-methyl-1H-1,2,3-triazol-4-yl]diphenyl-meth-an-ol and morpholine, consists of a subsituted triazolyl group and a morpholinyl group that crowd the aliphatic C atom of a diphenyl-methyl unit [C(triaz)-C-N(morph) = 110.1 (1)° and C(phen-yl)-C-C(phen-yl) = 103.9 (1)°]. The morpholine ring adopts a chair conformation.

Photosynthesis is not required for the toxicity of diphenyl ether herbicides, nor are chloroplast thylakoids the primary site of diphenyl ether herbicide activity. Isolated spinach (Spinacia oleracea L.) chloroplast fragments produced malonyl dialdehyde, indicating lipid peroxidation, when paraquat (1,1'-dimethyl-4,4'-bipyridinium ion) or diuron [3-(3,4-dichlorophenyl)-1,1-dimethylurea] were ad...

In the title compound, C(15)H(10)FIO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane through the benzofuran fragment. The 4-iodo-phenyl ring is rotated out of the benzofuran plane by a dihedral angle of 39.4 (1)°. The crystal structure is stabilized by an inter-molecular C-H⋯O hydrogen bond and an I⋯O halogen bond [3.055 (2) Å]. The cry...

In the title compound, C(14)H(15)BrO(4)S, the S atom has a distorted trigonal-pyramidal coordination. The O atom and the methyl group of the methyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment. The mol-ecules form slightly slipped π-stacked inversion-symmetric dimers by inter-molecular aromatic π-π inter-actions, with a centroid-to-centroid distance of 3.69...