Metal-doped diamond-like carbon films were produced for the purpose of an electrochemical nanoelectrode. In this study we use Z-contrast scanning transmission electron microscopy to directly observe metal cluster formation and distributions within the chromium-doped carbon films. At low doping ~;6 at. % Cr!, Cr is uniformly distributed within the C matrix; at high doping ~;12 at. % Cr!, Cr-rich...