A simple one-dimensional Monte Carlo model has been developed to simulate the chemical vapour deposition (CVD) of a diamond (100) surface. The model considers adsorption, etching/desorption, lattice incorporation, and surface migration along and across the dimer rows. The top of a step-edge is considered to have an infinite Ehrlich-Schwoebel potential barrier, so that mobile surface species can...

The manufacturing of chemical vapour deposition (CVD) diamond coated shaft type cutting tools is demanding due to the complex design of the cutting edges and the cobalt content of the cemented carbide. The influencing parameters of substrate, pre-treatment and diamond film on the tool cutting performance are discussed. The optimised manufacturing route of CVD diamond coated thread milling drill...

We demonstrate an approach, based on plasmonic apertures and gratings, to enhance the radiative decay rate of single NV centers in diamond, while simultaneously improving their collection efficiency. Our structures are based on metallic resonators formed by surrounding sub-wavelength diamond nanoposts with a silver film, which can enhance the spontaneous emission rate of an embedded NV center. ...

Electrostatic self-assembly of diamond nanoparticles (DNPs) onto substrate surfaces (so-called nanodiamond seeding) is a notable technique, enabling chemical vapor deposition (CVD) of nanocrystalline diamond thin films on non-diamond substrates. In this study, we examine this technique onto differently polarized (either Al- or N-polar) c-axis oriented sputtered aluminum nitride (AlN) film surfa...

Diamonds not only are beautiful and valuable as jewelry, they also have a number of unique characteristics that make them valuable in a range of commercial applications, including optics, acoustics, medicine, electronics, tooling and hard coatings, abrasives, and ceramics. Economic and technical constraints, however, limit their use. A low-cost method of depositing diamond film would open the w...

Most MEMS devices are currently based on silicon because of the available surface machining technology. However, Si has poor mechanical and tribological properties which makes it difficult to produce high performance Si based MEMS devices that could work reliably, particularly in harsh environments; diamond, as a superhard material with high mechanical strength, exceptional chemical inertness, ...

Diamond growth using a new low-pressure combustion technique is reported. A large-area hydrogen/oxygen flame is used as the source of atomic hydrogen. Methane diluted in hydrogen is injected into the flame near a heated silicon substrate, on which diamond crystallites nucleate and grow. This technique is potentially capable of large-area film growth, since atomic hydrogen can be generated unifo...

Heavily boron-doped, diamond films can become superconducting with critical temperatures Tc well above 4 K. Here we first measure the reflectivity of such a film down to 5 cm(-1), by also using coherent synchrotron radiation. We thus determine the optical gap 2Delta, the field penetration depth lambda, the range of action of the Ferrell-Glover-Tinkham sum rule, and the electron-phonon spectral ...

We report the observation of a very large piezoresistive effect in both polycrystalline and homoepitaxial chemical-vapor-deposited diamond films. The gauge factor for polycrystalline p-type diamond at 500 microstrains was found to be only 6 at room ambient, but increased rapidly with temperature, exceeding that of polycrystalline silicon (30) at 35 ‘C, and that of single-crystal Si (120) at 50 ...

Diamond films are prepared by microwave plasma-enhanced chemical-vapor deposition on Si 100 substrates using the H2–Ar–CH4 gases. Raman scattering data, including the peak position, intensity, area, and width, are analyzed in depth and used to obtain the sp3and sp2-bonded carbon contents and the nature of internal stresses in the films. Polarization behavior of the Raman peaks is analyzed to as...