Hydrogen peroxide as an oxidant agent was used for desulfurization of a petroleum hydrocarbon fraction (C10-C22) with boiling range of 175-375 ℃, (light fuel oil) in the presence of acetic acid as catalyst. The oxidation was performed in an ultrasonic bath. It is found that increasing the amount of hydrogen peroxide lead to increase the oxidation rate and so desulfurizatio...

the paper introducedeffects of modified pyrolysis tar on flue gas desulfurization. this experiment selected the pyrolysis tar as the raw material, researched the effects on desulfurization performance under different modification solution, concentration, solid liquid ratio of pyrolysis tar and modified solution, calcination temperature and calcination time by 16 group orthogonal experiments. th...

The desulfurization of gas streams using aqueous iron(II)sulfate (Fe(II)SO4), zinc sulfate (ZnSO4) and copper sulfate (CuSO4) solutions as washing liquor is studied theoretically and experimentally. The desulfurization is accomplished by a precipitation reaction that occurs when sulfide ions and metal ions are brought into contact with each other. A thermodynamic study has been used to determin...

Kinetic and isotopic methods were used to probe elementary steps and site requirements for thiophene hydrogenation and desulfurization on Ru metal clusters. Turnover rates for these reactions were unaffected by whether samples were treated in H2 or H2S to form metal and sulfide clusters, respectively, before reaction. These data, taken together with the rate and extent of sulfur removal from us...

1-ethyl-3-methylimidazolium ethyl sulfate [Etmim][EtSO4 ],1, 3-dimethylimidazolium methyl sulfate [Mmim][MeSO4 ] and 1-octyl-3-methylimidazolium nitrate [Omim][NO3 ] ionic liquids have been used in thermal oxidative desulfurization of model fuel oils consisting of 500 ppm solutions of benzothiophene (BT) and dibenzothiophene (DBT) in dodecane. The efficiency of sulfur removal from BT and DBT so...

In this paper, the effect of MgO, BaO, Na 2 O and SrO addition to a pre-melted CaO-Al2O3 -Si 2 O synthetic slag on sulfur removal from plain carbon steel was studied under the same experimental conditions. The slags were pre-melted at 1400°C in an electric resistant furnace and desulfurization experiments were carried out in a high frequency induction furnace. The results showed that ...