In this work, the eSAFT-VR Mie equation of state (EoS) is extended to low relative permittivity, non-aqueous solutions. The effect using different permittivity relations for electrolyte solutions studied, ranging from experimentally measured values a salt-composition independent permittivity. Furthermore, approaches characteristic diameters in Debye-Hückel and Born terms presented. EoS reparame...

Two first-principles simulation techniques, path integral Monte Carlo (PIMC) and density functional molecular dynamics (DFT-MD), are applied to study hot, dense helium in the densitytemperature range of 0.387 – 5.35 g cm and 500 K – 1.28×10 K. One coherent equation of state (EOS) is derived by combining DFT-MD data at lower temperatures with PIMC results at higher temperatures. Good agreement b...

In this paper, a simple but accurate modeling method for obtaining analytical solutions for the fundamental characteristics of electroosmotic ow through rectangular pumping channels without the Debye–Hückel approximation is presented. The Poisson–Boltzmann equation without the ebye–Hückel approximation for the electric potential distribution and the momentum equation for the velocity profile ar...

Near-critical thermodynamics in the hard-sphere (1, 1) electrolyte is well described, at a classical level, by Debye-Hückel (DH) theory with s1, 2d ion pairing and dipolar-pair-ionic-fluid coupling. But DH-based theories do not address density fluctuations. Here density correlations are obtained by functional differentiation of DH theory generalized to nonuniform densities of various species. T...

We study the free energy of a heavy quark-antiquark pair in a thermal medium. We constuct a simple ansatz for the free energy for two quark flavors motivated by the Debye-Hückel theory of screening. PACS. 11.15.Ha, 12.38.Mh, 25.75.Nq

In their seminal paper of 1923, Debye and Hückel provided the first appropriate description effect ionic strength on thermodynamic properties dilute electrolyte solutions. This landmark work paved way for what was later called primitive model electrolytes. At this level, an solution is modeled as a collection charged hard spheres in dielectric continuum that manifests itself only through its co...

We study the equations of a two dimensional incompressible Newtonian fluid coupled with a dispersive parabolic-elliptic system on bounded domains. Global in time weak solutions are shown to exist and converge with a rate to the stationary solution for L 2 initial data. This paper extends and improves on a body of work surrounding the Debye-Hückel system to the hydrodyanamical case.