cofecu nanowires were deposited by pulsed electrodeposition technique into the porous alumina templates by a two-step mild anodization technique, using the single-bath method. the electrodeposition was performed in a constant electrolyte while cu constant was controlled by electrodeposition current. the electrodeposition current was 3.5, 4.25, 5 and 6 ma. the effect of electrodeposition current...

We present evidence that in a very thin regime the magnetic layers become discrete islands and superparamagnetic in multilayered CoNi 1–17 nm /Cu 4.2 nm nanowires grown by pulsed electrodeposition using a hole pattern of anodized alumina templates. Magnetic hysteresis loops measured at room temperature using a vibrating sample magnetometer show that superparamagnetism appears at t CoNi 1.7 nm, ...

Alumina supported CuCl2, the basic catalyst for ethylene oxychlorination, has been investigated by UV-Vis spectroscopy, EPR, EXAFS and XANES in a wide range (0.25-9.0 wt%) of Cu concentration. We have evidenced that, at low Cu content, the formation of a surface aluminate species takes place. The formation of this surface copper aluminate stops at 0.95 wt% Cu / 100 m; at higher Cu concentration...

Benzene was hydroxylated with hydrogen peroxide (H2O2) in the presence of catalytic amounts of copper complexes in acetone to yield phenol at 298 K. At higher temperature, phenol was further hydroxylated with H2O2 by catalysis of copper complexes to yield p-benzoquinone. The kinetic study revealed that the rate was proportional to concentrations of benzene and H2O2, but to the square root of co...

In this study, molybdenum-copper/alumina nano composite was synthesized with mechano-chemical method using high energy planetary ball milling. The molybdenum oxide, copper oxide and aluminum powder were used as starting materials and reaction appeared to occur through a rapid combustion reaction process. The evaluation of powder particles after different milling times was studied by X-ray diffr...

This study investigates a hybrid nanofluid flow towards stagnation region of vertical plate with radiation effects. The consists copper (Cu) and alumina (Al2O3) nanoparticles which are added into water to form Cu-Al2O3/water nanofluid. point describes the fluid motion in solid surface. In this study, both buoyancy assisting opposing flows considered. similarity equations obtained using transfor...

• PdCu single atom alloys (SAA) selectively catalyse furfural hydrogenation. Successful deposition of Pd atoms on Cu nanoparticles via galvanic replacement. SAAs are catalytically superior to monometallic and catalysts. host enhance hydrogen dissociative adsorption. Single-atom catalysts serve as a skilful control precious metals heterogenous where all active sites accessible for catalytic reac...

Atomic layer deposition (ALD) of alumina using trimethylaluminum (TMA) has technological importance in microelectronics. This process has demonstrated a high potential in applications of protective coatings on Cu surfaces for control of diffusion of Cu in Cu2S films in photovoltaic devices and sintering of Cu-based nanoparticles in liquid phase hydrogenation reactions. With this motivation in m...

The dispersion and coordination of aluminium species on the surface of silica-alumina based materials are essential for controlling their catalytic activity and selectivity. Al and Al are two common coordinations of Al species in the silica network and alumina phase, respectively. Al is rare in nature and was found hitherto only in the alumina phase or interfaces containing alumina, a behavior ...