Great opportunities exist for Ion-Selective Electrodes (ISEs) in the fields of environmental monitoring and of wearable applications for example as the sensing part in wireless networks. In this review special attention is given to the recent results obtained with Solid Contact IonSelective Electrodes and Solid Contact Reference Electrodes. Their combination as disposable sensing platform may o...

Apparatus and techniques a re dc~cribed for t he t itration of ac ids a nd. bases by constantcurrent coulometry. The precision nnd accuraey of t he method aI~e JndLcated by tl traLlons of benzoic acid, potass ium acid pMhalate, adLpiC aCld, hydroc~lo l'l c aCid, ~nd sod ium eal'bonate. Standard deviations of ± 0.003 p er cent have been obtaIned which LndlCatp. that the reliabi li ty of the meth...

Serum iron concentrations greater than 90 mumol/L were measured in samples from hemodialysis patients by a Ferrozine dye-binding method. Reanalysis by coulometry showed these results to be spuriously high. Turbidity resulting from precipitation of fibrinogen was identified as the source of the interference. High concentrations of heparin enhanced the effect. We conclude that the persistence of ...

The electrooxidation of methylhydrazine, 1,2-dirnethylhydrazine, and 1,1 -dimethylhydrazine at a platinum electrode was studied using chronopotentiometry, coulometry, and product analysis. The results show that methjJlhydrazine is oxidized in an over-all four-electron reaction to nitrogen and methanol. The oxidation of 1,2-dimethylhydvazine proceeds by an initial two-electron oxidation, followe...

Conditions have been found for the determination of some phenoxazones by titanometric coulometry using platinum electrode to generate Ti(III) ions, while the point of equivalency was recorded potentiometrically. It has been found, that correct and accurate results can be obtained when the amount of ethanol in the coulometric vessel is within 2—7 ml and the amount of the substance determined is ...

The electroreduction of bovine serum albumin (BSA) in pH 7.4 solution was studied at the hanging mercury drop electrode by double potential step chronocoulometry and cyclic voltammetry. and at a mercury pool electrode by controlled potential coulometry. The proposed mechanism involves reduction of an adsorbed monolayer of BSA (maximum coverage 3.3 1lC-2); at short times 3 or 4 disulfide bonds a...

A scalable and rather inexpensive solution to producing microanalytical systems with "on-chip" three-dimensional (3D) microelectrodes is presented in this study, along with applicability to practical electrochemical (EC) detection scenarios such as preconcentration and interferant removal. This technique to create high-aspect-ratio (as much as 4:1) gold microstructures in constrained areas invo...