نتایج جستجو برای: coordination compounds

تعداد نتایج: 301536  

Journal: :Bioinorganic Chemistry and Applications 2005
Beatriz King-Díaz Josefina Montes-Ayala Concepción Escartín-Guzmán Silvia E. Castillo-Blum Roberto Iglesias-Prieto Blas Lotina-Hennsen Norah Barba-Behrens

In this work we present the synthesis, structural and spectroscopic characterization of Co(2+) coordination compounds with ethyl 4-methyl-5-imidazolecarboxylate (emizco). The effects of emizco, the metal salts CoCl(2).6H(2)O, CoBr(2), Co(NO(3))(2).6H(2)O and their metal coordination compounds [Co(emizco)(2)Cl(2)], [Co(emizco)(2) Br(2)].H(2)O, [Co(emizco)(2) (H(2)O)(2)(NO(2))(2).2H(2)O were eval...

Journal: :Dalton transactions 2010
Tao Wu Cheng-Hui Li Yi-Zhi Li Zhao-Gui Zhang Xiao-Zeng You

A couple of enantiomers of novel chiral macrocyclic imines based on R/S-camphor were asymmetrically synthesized. Through the chiral macrocyclic ligands, enantiomers of nickel(II) coordination compounds were obtained. The chirality of the ligand was transferred to the nickel atom upon coordination, leading to predetermined configuration. The chiral ligands and corresponding nickel coordination c...

Journal: :Acta Crystallographica Section A Foundations of Crystallography 1996

2013
Philipp Gütlich Ana B Gaspar Yann Garcia

The article deals with coordination compounds of iron(II) that may exhibit thermally induced spin transition, known as spin crossover, depending on the nature of the coordinating ligand sphere. Spin transition in such compounds also occurs under pressure and irradiation with light. The spin states involved have different magnetic and optical properties suitable for their detection and character...

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