The Catskill Mountains of southeastern New York receive relatively high rates of atmospheric N deposition, and NO3 concentrations in some streams have increased dramatically since the late 1960s. We measured the chemistry of 39 firstand second-order streams with forested watersheds to determine the variability of nitrogen concentrations within the Catskill Mountain area. We found that some stre...

Gas-phase plutonium nitrate anion complexes were produced by electrospray ionization (ESI) of a plutonium nitrate solution. The ESI mass spectrum included species with all four of the common oxidation states of plutonium: Pu(III), Pu(IV), Pu(V), and Pu(VI). Plutonium nitrate complexes were isolated in a quadrupole ion trap and subjected to collision-induced dissociation (CID). CID of complexes ...

OBJECTIVE To develop a coated electrode of immobilized denitrificants and to evaluate the performance of a bioelectrochemical reactor to enhance and control denitrification. METHODS Denitrifying bacteria were developed by batch incubation and immobilized with polyvinyl alcohol (PVA) on the surface of activated carbon fiber (ACF) to make a coated electrode. Then the coated electrode (cathode) ...

the present study investigated no3- and br- contamination in groundwater of arak aquifer of markazi province. correlation and factor analysis were used to detect interrelation and sources of concentration of no3- and br- ions and others physicochemical variables. no correlation was observed between no3- and others contents, but positive correlation was identified between br- with other major va...

In Arabidopsis the plasmamembrane nitrate transceptor (transporter/receptor) NRT1.1 governs many physiological and developmental responses to nitrate. Alongside facilitating nitrate uptake, NRT1.1 regulates the expression levels of many nitrate assimilation pathway genes, modulates root system architecture, relieves seed dormancy and protects plants from ammonium toxicity. Here, we assess the f...

In papers by Wang et al. (1998), Liu et al. (1999), and Liu and Tsay (2003), it was proposed that Arabidopsis thaliana Nitrate Transporter1.1 (AtNRT1.1; CHL1) encodes a dual-affinity nitrate transporter that “plays a major role in high-affinity nitrate uptake.” Here, we evaluate this concept by reexamining the uptake kinetics of Arabidopsis (Arabidopsis thaliana) mutant lines defective in NRT1....

Understanding the mechanistic controls of microbial denitrification is of central importance to both environmental microbiology and ecosystem ecology. Loss of nitrate (NO3) is often attributed to carbon-driven (heterotrophic) denitrification. However, denitrification can also be coupled to sulfur (S) oxidation by chemolithoautotrophic bacteria. In the present study, we used an in situ stable is...

The photochemistry of nitrate ions in bulk aqueous solution is well known, yet recent evidence suggests that the photolysis of nitrate may be more efficient at the air-water interface. Whether and how this surface enhancement is altered by the presence of different cations is not known. In the present studies, thin aqueous films of nitrate salts with different cations were deposited on the wall...

Highly oxidizing nitrate radicals (NO3˙) are easily accessed from readily available nitrate salts by visible light photoredox catalysis using a purely organic dye as the catalyst and oxygen as the terminal oxidant. The interaction of the excited catalyst and nitrate anions was studied by spectroscopic methods to elucidate the mechanism, and the method was applied to the NO3˙ induced oxidation o...