A new Determining Horvath-Kawazoe (DHK) program for the evaluation of pore-size distribution curve based on the HK method (J. Chem. Eng. Jpn. 16 (1983) 470) is described. The standard bisection procedure (Gerald, C.F., 1977. Applied Numerical Analysis, 2nd ed. Addison-Wesley, CA) is used as a kernel in the proposed algorithm. The calculation of the effective pore-size distribution and the compa...

Contemporary medical and dental adhesives often have difficulty sticking to wet surfaces or weaken with long-term exposure to water. Substantial research has been dedicated to finding a means of achieving adhesion in an aqueous environment. A study evaluates the adsorption of catechol relative to other chemical groups as means of gauging how effective they may be as adsorptive groups in adhesiv...

The application of molecular imprinting technology in the separation and purification of active ingredients in natural products was widely reported, but remains a challenge. Enrichment and separation are especially limited. A surface imprinting technique was reported to synthesize molecularly imprinted microspheres (MIMs) in this article. With paeoniflorin (PF) as the template molecule, β-cyclo...

Thermal batteries based on a reversible adsorption/desorption of a working fluid (water, methanol, ammonia) rather than the conventional vapor compression is a promising alternative to exploit waste thermal energy for heat reallocation. In this context, there is an increasing interest to find novel porous solids able to adsorb a high energy density of working fluid under low relative vapor pres...

Density functional theory has been used to perform a comparative theoretical study of the adsorption and dissociation of H(2)O monomers and icelike bilayers on Ru[0001]. H(2)O monomers bind preferentially at atop sites with an adsorption energy of approximately 0.4 eV/H(2)O. The main bonding interaction is through the H(2)O 1b(1) molecular orbital which mixes with Ru d(z)2 states. The lower-lyi...

The objective of this study was to compare the adsorption/desorption of target compounds on homemade electrospun nanofibers, polystyrene (PS) nanofibers, acrylic resin (AR) nanofibers and PS-AR composite nanofibers with Tenax TA. Ten volatile organic compounds (VOCs) were analyzed by preconcentration onto different sorbents followed by desorption (thermal and solvent orderly) and analysis by ca...

Binary and ternary hybrid systems of ZnO possessing nanoparticle and nanorod morphologies on reduced graphene oxide (rGO) and rGO with Au nanoparticles are explored as photocatalysts and a comparative study of their photodegradation performance is presented. Various preparation methods such as solution phase and hydrothermal routes have been employed to produce rGO-ZnO hybrids and rGO-Au-ZnO hy...

Methane adsorption onto single-wall boron nitride nanotubes (BNNTs) and carbon nanotubes (CNTs) was studied using the density functional theory within the generalized gradient approximation. The structural optimization of several bonding configurations for a CH4 molecule approaching the outer surface of the (8,0) BNNT and (8,0) CNT shows that the CH4 molecule is preferentially adsorbed onto the...