The present approach for determining the electrophilicity (E) and nucleophilicity (N) of aldehydes includes a kinetic study of KMNO4 oxidation and NaBH4 reduction of aldehydes. A transition state analysis of the KMNO4 promoted aldehyde oxidation reaction has been performed, which shows a very good correlation with experimental results. The validity of the experimental method has been tested usi...

Plastic materials are commonly used for storing food stuffs and medicines. Chemical substances used in the manufacture of plastic goods are found to migrate in the food stuffs used. The migration of UV absorbents and oxidisable matter was found to be more when used for longer periods.

OBJECTIVES To describe the pediatric interview as it is conducted in different practice settings and with children ranging in age from infancy to adolescence, and to identify pediatric history-taking strategies that varied across age groups. PARTICIPANTS AND METHODS A self-administered survey was designed and mailed to a group of pediatricians in the Chicago metropolitan area to assess common...

Seventeen commonly used dyes and 16 of their metabolites or derivatives were tested in the Salmonella-mammalian microsome mutagenicity test. Mutagens active with and without added Aroclor-induced rat liver microsome preparations (S9) were 3-aminopyrene, lithol red, methylene blue (USP), methyl yellow, neutral red, and phenol red. Those mutagenic only with S9 activation were 4-aminopyrazolone, 2...

This paper reports two studies which investigated the effect of interference on delayed recall scores of the WMS-III and other commonly used memory measures. In Study 1, participants completed the immediate and delayed components of the WMS-III, with or without the introduction of conceptually similar memory tasks between the recall trials. In Study 2, this order of administration was reversed,...

The goal of this project was to develop a structured process for evaluating the capability of simulators to support mariner performance assessment. In this approach, simulator evaluation objectives and criteria are based on performance-based mariner assessment requirements. The approach produces a simulator evaluation protocol that addresses four areas of simulator capability: (1) providing fle...

Software simulators that emulate equivalent behavior of physical microcontrollers play an important role in the process of software development for embedded systems from an early development stage (e.g. when no target hardware is available) to the final verification process (e.g. used in combination with formal methods). Thus, much reliance is put on the correctness of these simulators. This pa...