The structures of five polyiodide salts, [Co([9]aneS3)2]I11 (1), [Ni([9]aneS3)2]I6 (2), [Ni([9]aneS3)2]I10 (3), [Pd([12]aneS4)]I6 (4) and [Pd([14]aneS4)]I10.MeCN (5), containing the template cations [Co([9]aneS3)2]3+, [Ni([9]aneS3)2]2+, [Pd([12]aneS4)]2+ and [Pd([14]aneS4)]2+ ([9]aneS3=1,4,7-trithiacyclononane, [12]aneS4=1,4,7,10-tetrathiacyclododecane, [14]aneS4=1,4,8,11-tetrathiacyclotetradec...

[κ2-O,O′-Carbonatotetraamminecobalt(III)] iodide, or [Co(NH3)4CO3]I, named in this paper as compound 1, was prepared and characterized comprehensively with spectroscopic (IR, Raman UV) single-crystal X-ray diffraction methods. Compound 1 orthorhombic, isomorphous the analogous bromide. The four ammonia ligands carbonate anion were coordinated to central cobalt cation a distorted octahedral geom...

The mononuclear cobalt complex of 3,5-di-tert-butylcathecolate and cyan-pyridine (Co(diox)2(4-CN-py)2) is a very versatile compound that displays valence tautomerism (VT) in the solid state, which induced by temperature, light, hard X-rays, modulated solvent crystal lattice. In our work, we used single X-ray diffraction as probe for light-induced VT state demonstrate controlled use X-rays via a...

Catalytic activity and stability of iron hexacyanocobaltate (FeIII[CoIII(CN)6], Fe–Co) for organophosphate hydrolysis are improved by doping divalent metal ions (MII = MnII, NiII, or CuII). The catalytic a series (FeIII0.8MII0.3)[CoIII(CN)6] (FeM–Co compounds) was examined in mixed solution water ethanol [9:1 (v/v)] containing disodium p-nitrophenyl phosphate (p-NPP) at 60 °C. FeM–Co compounds ...

Experimental Section General procedure for synthesis of thiazolines: Trifluoromethanesulfonic anhydride (50 mL, 0.3 mmol) was added slowly to a solution of triphenylphosphane oxide (167 mg, 0.6 mmol) in dry CH2Cl2 (2 mL) at 0 8C. The reaction mixture was stirred for 10 min at 0 8C and then adjusted to the desired reaction temperature, followed by addition of the fully protected cysteine N-amide...