Nanoparticles of coordination polymer [Co2(pydc)2(H2O)6]n.2n H2O [H2pydc = pyridine-2,5-dicarboxylic acid] have been synthesized by sonochemical method and characterized by elemental analysis, infrared spectroscopy, powder X-ray diffraction, scanning electron microscopy, DLS particle size analysis and TGA/DTA. The structure of single crystalline coordination polymer developed from nanosized coo...

nanoparticles of coordination polymer [co2(pydc)2(h2o)6]n.2n h2o [h2pydc = pyridine-2,5-dicarboxylic acid] have been synthesized by sonochemical method and characterized by elemental analysis, infrared spectroscopy, powder x-ray diffraction, scanning electron microscopy, dls particle size analysis and tga/dta. the structure of single crystalline coordination polymer developed from nanosized coo...

[1] Knowledge about the properties of silicate melts is needed by volcanologists and petrologists to evaluate the dynamics of volcanic eruptions and magmatic processes. These properties include the solubility and diffusivity of volatile components in silicate melts, silicate melt viscosity, and the fragmentation condition. Data and models of each property are reviewed and assessed. For rhyoliti...

Ammonia was used for the major absorbent while sodium hydroxide was used as a reference in either a bubble column (semi-batch reaction) or a packed tower (continuous reaction) to absorb CO2 in this study. In the bubble column, bubbling time as a function of temperature, pH, and dissolved inorganic carbon concentration in the solution was measured to see the characteristics of the reaction and t...

the mononuclear gd(iii) complex, [gd(l)3(h2o)5] (where l is alizarin yellow r (nac13h8n3o5)), has been prepared in h2o under reflux condition. the gd(iii) complex has been characterized by elemental analysis and spectroscopic methods (uv–vis and ft–ir). the gd2o3 nanoparticles were prepared by the calcination of the gd(iii) complex in air at different temperatures up to 600 °c for 2 h. the calc...

The enthalpy of dissociation is an important property of clathrate hydrates. Through it is possible to obtain some conclusions about the microscopic structure formed. It can be obtained by direct methods of measurement or estimated by indirect methods. However, the inherent difficulties of direct methods influence the accuracy of this methodology. Given this, the direct or indirect methods show...

This work investigates the pore development in biochar during gasification using synchrotron small angle X-ray scattering (SAXS) as an situ characterization technique. The influence of gasifying agents (H2O, CO2 or H2O/CO2) and temperature on structure was studied by carrying out hour-long mallee wood (106–250 μm) in: (i) H2O at 700, 800 900 °C respectively, (ii) 700 °C, (iii) a mixture (H2O/CO...

Several reactions, known from other amine systems for CO2 capture, have been proposed for Lewatit R VP OC 1065. The aim of this molecular modeling study is to elucidate the CO2 capture process: the physisorption process prior to the CO2-capture and the reactions. Molecular modeling yields that the resin has a structure with benzyl amine groups on alternating positions in close vicinity of each ...