The adsorption and speciation of U(VI) was investigated on contaminated, fine grained sediment materials from the Hanford 300 area (SPP1 GWF) in simulated groundwater using cryogenic laser-induced U(VI) fluorescence spectroscopy combined with chemometric analysis. A series of reference minerals (montmorillonite, illite, Michigan chlorite, North Carolina chlorite, California clinochlore, quartz ...

Chlorite dismutases (Clds) are heme b containing oxidoreductases that convert chlorite to chloride and molecular oxygen. In order to elucidate the role of conserved heme cavity residues in the catalysis of this reaction comprehensive mutational and biochemical analyses of Cld from "Candidatus Nitrospira defluvii" (NdCld) were performed. Particularly, point mutations of the cavity-forming residu...

Chlorite is a serious environmental concern, as rising concentrations of this harmful anthropogenic compound have been detected in groundwater, drinking water, and soil. Chlorite dismutases (Clds) are therefore important molecules in bioremediation as Clds catalyze the degradation of chlorite to chloride and molecular oxygen. Clds are heme b-containing oxidoreductases present in numerous bacter...

Chlorite flakes, as a product of alteration of biotite, the dominant ferromagnesian mineral in the Paleozoic granitic rocks of the Canadian Appalachians, have been analyzed by electron microprobe for major elements and by 57Fe M?ssbauer spectroscopy for the coordination and oxidation state of Fe. Comparison of M?ssbauer Fe3+/Fe ratios obtained from chlorite and its host biotite indicates that c...

It is demonstrated that cyanobacteria (both azotrophic and non-azotrophic) contain heme b oxidoreductases that can convert chlorite to chloride and molecular oxygen (incorrectly denominated chlorite 'dismutase', Cld). Beside the water-splitting manganese complex of photosystem II, this metalloenzyme is the second known enzyme that catalyses the formation of a covalent oxygen-oxygen bond. All cy...

Abdel-Rahman MS, Scatina J. 1985. The effect of Alcide ® , a new antimicrobial drug, on rat blood glutathione and erythrocyte osmotic fragility, in vitro.

The primary purpose of this chapter is to provide public health officials, physicians, toxicologists, and other interested individuals and groups with an overall perspective on the toxicology of chlorine dioxide and chlorite. It contains descriptions and evaluations of toxicological studies and epidemiological investigations and provides conclusions, where possible, on the relevance of toxicity...

In this study, clay and non-clay minerals in the cement of Cretaceous volcanogenic–sedimentary rocks from bottom marginal seas north-western Pacific Ocean adjacent areas were studied. Corrensite mixed-layer chlorite–smectite, rectorite illite–smectite, chlorite, swelling chlorite (?), illite, kaolinite, smectite calcite, ankerite, barite, gypsum, epsomite, zeolites (laumontite, analcime, stilbi...