We have analyzed Atacama Large Millimeter/submillimeter Array (ALMA) Cycle 4 Band 6 data toward two young stellar objects (YSOs), Oph-emb5 and Oph-emb9, in the Ophiuchus star-forming region. The YSO is located a relatively quiescent region, whereas Oph-emb9 irradiated by nearby bright Herbig Be star. Molecular lines from $cyclic$-C$_{3}$H$_{2}$ ($c$-C$_{3}$H$_{2}$), H$_{2}$CO, CH$_{3}$OH, $^{13...