Two DTPA derivatives, a mono-amide derivative containing an iodinated synthon, DTPA-IOPsp (L ) and the ligand DTPA(BOM) 1 3 153 31 111 31 (BOM5benzyloxymethyl) (L ), radiolabelled with Sm and In , were studied as potential hepatospecific gamma scintigraphic 2 agents. In vivo studies with Wistar rats show that the main excretory pathway for all the chelates studied is the hepatobiliary system. T...

Diazacrown ethers having two carbodithioate groups were synthesized, and their spectrophotometric properties were studied. Diammonium 1,4,10,13-tetraoxa-7,16-diazacycrooctadecane-N,N'-bis(carbodithioate) (DA18CC) and ammonium 1,4,10-trioxa-7,13-diazacycropentadecane-N,N'-bis(carbodithioate) (DA15CC) reacted with most heavy-metal ions through their two carbodithioate groups, and also reacted wit...

A series of group III metal chelates have been synthesized and characterized for the versatile application of organic light-emitting diodes (OLEDs). These metal chelates are based on 4-hydroxy-1,5-naphthyridine derivates as chelating ligands, and they are the blue version analogues of well-known green fluorophore Alq(3) (tris(8-hydroxyquinolinato)aluminum). These chelating ligands and their met...

of various physicochemical and spectroscopic measurements using various indicator compounds. 1–6 Especially, three parameters, dielectric constant, DC, donor number, DN, and acceptor number, AN serve as fundamental and extensive set for applications. However, it is not easy to directly derive these parameters by means of the original measurement method. It is expected that they can be predicted...

A series of bis-, tris- and tetra-phosphonated pyridine ligands is presented. In view of their potential use as chelates for radiopharmaceutical applications, the physico-chemical properties of the ligands and of their Co(II), Ni(II), Cu(II), and Zn(II) complexes were studied by means of potentiometry and UV-Vis absorption spectroscopy. The pKa values of the ligands and of the complexes, as wel...

A comparison between two fluorescent metal chelates for staining proteins separated by electrophoresis has been carried out. One of these chelates is ruthenium II tris (bathophenanthroline disulfonate) and the other is commercial Sypro Ruby. Both can be efficiently detected either with UV tables or with commercial laser fluorescence scanners. The sensitivity and homogeneity of the stains and th...

New complexes of Al(III), Fe(III), Co(III), Rh(III), In(III) and Zr(IV) with 1-phenyl3-methyl-4-trifluoroacetyl-pyrazolone-5, (HPMTFP), have been synthesized and characterized by means of elemental analyses, conductivity and magnetic moment measurements, proton NMR and infrared spectroscopy. It is concluded that the ligand, HPMTFP, reacts as a bidentate enol forming neutral metal chelates. The ...

B. Anionic Ligands 302 IX. Group 9 Catalysts 302 X. Group 10 Catalysts 303 A. Neutral Ligands 303 1. R-Diimine and Related Ligands 303 2. Other Neutral Nitrogen-Based Ligands 304 3. Chelating Phosphorus-Based Ligands 304 B. Monoanionic Ligands 305 1. [PO] Chelates 305 2. [NO] Chelates 306 3. Other Monoanionic Ligands 306 4. Carbon-Based Ligands 306 XI. Group 11 Catalysts 307 XII. Group 12 Catal...