Activated carbon (AC) air-cathodes are inexpensive and useful alternatives to Pt-catalyzed electrodes in microbial fuel cells (MFCs), but information is needed on their long-term stability for oxygen reduction. AC cathodes were constructed with diffusion layers (DLs) with two different porosities (30% and 70%) to evaluate the effects of increased oxygen transfer on power. The 70% DL cathode ini...

Nano-sized and micron-sized LiFePO4 electrode materials were prepared by a sol gel and coprecipitation reactions. An improvement of the cycling and rate performances in lithium cells was observed for the carbon coated LiFePO4 materials. The coating process uses a solid/gas-phase reaction which consists of decomposing propylene gas, as carbon source, inside a reactor containing olivine LiFePO4 m...

the fuel cells are distinguished as generating of green allocable energy and are electrochemical devices of low environmental impact. porous nanocrystalline strontium-doped lanthanum manganite la0.8sr0.2mno3 (lsm) cathode materials were prepared by mechanochemical route in various grinding times. carbon black was employed to produce pores. the formation of lsm single phase was studied by x-ray ...

Dr. L. Liu, Prof. X. Li, Dr. S.-H. Bo, Dr. Y. Wang, Dr. N. Twu, Prof. G. Ceder Department of Materials Science and Engineering Massachusetts Institute of Technology Cambridge , MA 02139 , USA E-mail: gceder@mit.edu Prof. X. Li John A. Paulson School of Engineering and Applied Sciences Harvard University Cambridge , MA 02138 , USA Prof. H. Chen The Woodruff School of Mechanical Engineering Georg...

The development of manganese dioxide as the cathode for aqueous Zn-ion battery (ZIB) is limited by the rapid capacity fading and material dissolution. Here, a highly reversible aqueous ZIB using graphene scroll-coated α-MnO2 as the cathode is proposed. The graphene scroll is uniformly coated on the MnO2 nanowire with an average width of 5 nm, which increases the electrical conductivity of the M...

All-inorganic solid-state sodium-sulfur batteries (ASSBs) are promising technology for stationary energy storage due to their high safety, high energy, and abundant resources of both sodium and sulfur. However, current ASSB shows poor cycling and rate performances mainly due to the huge electrode/electrolyte interfacial resistance arising from the insufficient triple-phase contact among sulfur ...

In this work, the effect of the concentration-dependent chemical-expansion coefficient, b, on the chemo-elastic field in lithium-ion cathode particles is examined. To accomplish this, an isotropic linear-elastic model is developed for a single idealistic particle subjected to potentiostatic-discharge and charge conditions. It is shown that b can be a key parameter in demarcating the chemo-stres...