Catalyst layers (4-20 microm) of rhodium (1 wt%) supported on alumina, titania, and ceria-zirconia (Ce(0.5)Zr(0.5)O(2)) were coated on stainless-steel corrugated sheets by dip-coating in very stable colloidal dispersions of nanoparticles in water. Catalytic performances were studied for low-temperature (< or = 500 degrees C) steam reforming of propane at a steam to carbon ratio equal to 3 and l...

Direct Reduction processes use gases (CO and H2) for iron reduction production of sponge or direct reduced (DRI). The generation this gas occurs through methane reforming, which can be done in a reformer inside the shaft with as catalyst. latter auto-reforming processes. kinetics steam reforming catalyzed by was studied at temperatures between 875°C 1050°C. Results showed that acts catalyst con...

Catalytic reforming is a chemical process utilized in petroleum refineries to convert naphtha, typically having low octane ratings, into high octane liquid products, called reformates, which are components of high octane gasoline. In this study, a mathematical model was developed for simulation of semi-regenerative catalytic reforming unit and the result of the proposed model was compared with ...

Introduction Hydrogen as a fuel has recently been an important issue due to developments in fuel cell technology. Hydrogen production from sustainable sources, e.g. biomass, is gaining attention for a CO2 neutral energy supply. Recent developments in flash pyrolysis technologies make it possible to convert lignocellulosic biomass efficiently to a bio-oil, which is easier for handling and transp...

Hydrogen is the preferred fuel for fuel cells due to high reactivity for electrochemical reaction at anode. In the present study, a three dimensional CFD (Computational Fluid Dynamics) code was developed and validated to simulate the performance of a catalytic monolith fuel processor used for hydrogen generation. Methane autothermal reforming on 5% Ru/ -Al2O3 catalyst was selected as the reacti...

The aim of this work was the evaluation of the catalytic steam reforming of a gaseous fuel obtained by steam biomass gasification to convert topping atmosphere residue (TAR) and CH4 and to produce pure H2 by means of a CO2 sorbent. This experimental work deals with the demonstration of the practical feasibility of such concepts, using a real woodgas obtained from fluidized bed steam gasificatio...

Glycerol is the main byproduct of biodiesel production and its increased production volume derives from the increasing demand for biofuels. The conversion of glycerol to hydrogen-rich mixtures presents an attractive route towards sustainable biodiesel production. Here we explored the use of Pt/Al(2)O(3)-based catalysts for the catalytic steam reforming of glycerol, evidencing the influence of L...

Introduction Fuel cells, which produce electricity directly from hydrogen and oxygen, offer a clean and efficient potential alternative to internal combustion engines for generating power for portable and transportation applications. However, there currently is no infrastructure for the wide scale production and distribution of hydrogen to the transportation market. Instead of building new infr...

Introduction Steam reforming is a process that converts hydrocarbon fuels into hydrogen and oxygenated carbon species. This process is important for catalytic hydrogen production and for direct electrochemical reforming of hydrocarbons over high temperature fuel cells, such as Solid Oxide Fuel Cells (SOFCs). One of the main problems associated with the process is that conventional reforming (el...

A fine layered nanocomposite with a total thickness of about 200 nm was formed on the surface of an Al63Cu25Fe12 quasicrystal (QC). The nanocomposite was found to exhibit high catalytic performance for steam reforming of methanol. The nanocomposite was formed by a self-assembly process, by leaching the Al-Cu-Fe QC using a 5 wt% Na2CO3 aqueous solution followed by calcination in air at 873 K. Th...