A new scheme is presented for the preparation of 3~(4-chlorophenyl)5,7-dichloro-l-methylnaphthalene, from which, four derivatives, 3~(4-chlorophenyl)-~-di(n-butyl)aminomethyl~5,7-dichloro-l-naphthalene, ·, methanol hydrochloride, 3-(4-chlorophenyl)-5,7-dichloro-~-(2-piperidyl)1-naphthalenemethanol acetate, l-[3-(4-chlorophenyl)-5,77dichloro-lnaphthyl]-3-di(n-butyl)aminopropanol hydrochloride, a...

the behavior of nanoscale energetic materials is quite different from micronsized energetic materials inmany ways. recently, some techniques such as sol-gel method, high speed air impaction and vacuum codeposition have been employed to obtain nanoscale energetic materials. however, only few attentionswere paid to nanoscale energetic materials because of the fabrication difficulty. in this paper...

The acid property of alkali and alkali earth cation exchanged clinoptiolites were observed by micro-calorimetry of NH(3) adsorption at 200 degrees C. The reaction rates on decomposition of tert-butyl acetate (TBA) over clinoptilolites was proportional to the acid strength. 1,4-Dihydropyridines were oxidized to corresponding Pyridines in high yields at room temperature by H(2)O(2) aqueous soluti...

The biocidal activity of 8 triorganotins R3S11X (R = butyl, phenyl, benzyl; X = oxide, chloride, acetate, naphthenate, TV, JV-diethyldithiocarbamate) on brown rot fungi, moulds mixture, benthic organisms, plankton alga Scenedesmus quadricauda, and crop plant has been investigated. The results suggest dependence between lipophilicity of bounded R groups and intensity of unfavourable effect. The ...

The Sn atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(8)H(14)NO(2)S(2))], is coordinated by three chlorobenzyl ligands and one carboxylate O atom of the substituted acetate ligand in a distorted tetra-hedral environment. Three of the C atoms of the n-butyl group are disordered over two sites with equal occupancies.

Gaseous CO(2) is almost irreversibly absorbed by the room temperature ionic liquid 1-butyl-3-methylimidazolium acetate ([C(4)mim][Ac]) in which it undergoes a chemically irreversible, one electron electrochemical reduction, suggesting a means for the sequestration of the greenhouse gas.

The partition coefficients, Kmim, of N-methylimidazole (mim) in two-component systems composed of ionic liquid (IL) and a series of organic solvents immiscible with ILs (butyl acetate, ethyl acetate, tert-butyl methyl ether, diethyl ether and cyclohexane) were determined by a shake-flask method. The influence of different factors such as temperature, solvent polarity, mim concentration, and wat...

The transformation of methyl tert-butyl ether ~MTBE! and tert-amyl methyl ether ~TAME! using bifunctional aluminum in the presence of dioxygen ~O2! has been examined. Bifunctional aluminum, prepared by sulfating zero-valent aluminum with sulfuric acid, is an innovative extension of zero-valent metal technology. It has a dual functionality of simultaneously decomposing both reductively and oxida...

The aim of this study is to investigate ionic liquids (ILs) pretreatment on kempas composition, structure and enzymatic digestibility. Ground kempas (Koompassia malaccensis) was pretreated with 1-butyl-3-methylimidazolium acetate ([Bmim][OAc]), 1-butyl-3-methylimidazolium chloride ([Bmim]Cl) and 1-butyl-3-methylimidazolium trifluoromethansulfonate ([Bmim][OTf]), at 120°C for 6 and 12 h. The cel...

Bifunctional aluminum is prepared by sulfating aluminum metal with sulfuric acid. The use of bifunctional aluminum to degrade methyl tert-butyl ether (MTBE) in the presence of dioxygen has been examined using batch systems. Primary degradation products were tert-butyl alcohol, tert-butyl formate, acetone, and methyl acetate. The initial rate of MTBE degradation exhibited pseudo-first-order beha...