6-Substituted pyrrolo-dC-pyrrolo-dC mismatches selectively capture silver ions to form extraordinarily stable metal-mediated base pairs. One single modification in a 12-mer duplex causes a Tm increase of 36.0 °C relative to the metal-free mismatched duplex. Spectrophotometric titrations as well as ESI mass spectra confirmed the binding of two silver ions per base pair. The Ag(+)-mediated base p...

two n4-type schiff base ligands named n,n'-bis(2-pyridylmethylidene)-1,2-diiminoethane (l1) and n,n'-bis(2-pyridylmethylidene)-1,3-diiminopropane (l2) have been synthesized by the reaction of pyridine-2-carbaldehyde with ethylenediamine and propylenediamine, respectively. the binding abilities of l1 and l2 in dichloromethane towards cu2+, cd2+, co2+, ni2+, zn2+ and pb2+ ions were evaluated by p...

The DNA lesion 1,N(6)-ethenoadenine (εA) has been investigated with respect to its metal-binding properties. A synthetic DNA duplex comprising an εA : εA mispair readily forms doubly silver(I)-mediated base pairs εA-Ag(I)2-εA, representing the first example for a dinuclear metal-mediated homo base pair of a purine derivative. It also constitutes the first example for a Hoogsteen-type metal-medi...

Shield metal arc welding on the high strength low alloy steels in pipelines to transport natural gas from Iran is of great importance. In this article the effects of annealing heat treatment on properties of multi pass welding in different situations (6-4:30 , 4:30-3 , 3-1:30 , 1:30-12) with 36 in outside diameter is evaluated by chemical,  metallography, tensile, toughness and hardness. Tensil...

The ever-growing price of precious metals has promoted the widespread use of nickel and copper in the internal electrodes and end terminations of multilayer ceramic capacitors (MLCCs). While these base metal electrode (BME) capacitors are less expensive than capacitors made with palladium and silver/palladium, their unique production process produces an identifiable wear-out mechanism. Highly a...

A Schiff base was prepared from the interaction of ethanolic solutions of 2-hydroxy-1– naphthaldehyde and butylenediamine. The complexes were synthesized by refluxing the mixture of ethanolic solutions of the Schiff base and respective metal (II) chloride. Their solubility, melting point/decomposition temperature, molar conductance, elemental analysis and IR were carried out. The melting point ...