An in-depth account of the effects of homonuclear couplings and multiple heteronuclear couplings is given for a recently published technique for (1)H--(13)C dipolar correlation in solids under very fast MAS, where the heteronuclear dipolar coupling is recoupled by means of REDOR pi-pulse trains. The method bears similarities to well-known solution-state NMR techniques, which form the framework ...

Using the framework of potential energy landscape theory, we describe two in silico designs for self-assembling helical colloidal superstructures based upon dipolar dumbbells and Janus-type building blocks, respectively. Helical superstructures with controllable pitch length are obtained using external magnetic field driven assembly of asymmetric dumbbells involving screened electrostatic as we...

Recently achieved two-component dipolar Bose-Einstein condensates open exciting possibilities for the study of mixtures ultra-dilute quantum liquids. While non-dipolar self-bound are necessarily miscible with an approximately fixed ratio between two densities, density case is free. As a result, present qualitatively novel and much richer physics, characterized by three possible ground-state pha...

Metal nanoparticles are efficient resonant plasmonic scatterers for light, and, if placed on top of a high-index substrate, can efficiently couple light into the substrate. This coupling, however, strongly depends on particle shape and surrounding environment. We study the effect of particle shape and substrate refractive index on the plasmonic resonances of silver nanoparticles and we systemat...

Two robust combinations of spectral editing techniques with 2D (13)C-(13)C NMR have been developed for characterizing the aromatic components of (13)C-enriched low-temperature carbon materials. One method (exchange with protonated and nonprotonated spectral editing, EXPANSE) selects cross peaks of protonated and nearby nonprotonated carbons, while the other technique, dipolar-dephased double-qu...

Using dark-field scattering spectroscopy, we study the multipolar plasmon resonances in single crystallized silver nanorods. The lineshapes and homogenous linewidths of the surface plasmon resonances (SPRs) of different orders are analyzed and compared. The high-order resonances are found to sustain asymmetric Fano lineshapes and their linewidths are narrower than the dipolar resonance. A quant...

We present a new method for determining the orientation of chemical shift tensors in polycrystalline solids with site resolution and demonstrate its application to the determination of the Calpha chemical shift tensor orientation in a model peptide with beta-sheet torsion angles. The tensor orientation is obtained under magic angle spinning by modulating a recoupled chemical shift anisotropy (C...

Synthesis and structural characterization of two novel symmetrical banana mesogens built from resorcinol with seven phenyl rings linked by ester and imine with a terminal dodecyl/dodecyloxy chain has been carried out. Density functional theory (DFT) has been employed for obtaining the geometry optimized structures, the dipole moments and (13)C NMR chemical shifts. The HOPM and DSC studies revea...

NMR measurements of a large set of protein backbone one-bond dipolar couplings have been carried out to refine the structure of the third IgG-binding domain of Protein G (GB3), previously solved by X-ray crystallography at a resolution of 1.1 A. Besides the commonly used bicelle, poly(ethylene glycol), and filamentous phage liquid crystalline media, dipolar couplings were also measured when the...

Symmetry breaking of the excited state of a linear quadrupolar acceptor-donor-acceptor molecule was investigated using time-resolved infrared spectroscopy in 55 solvents allowing the influence of several solute-solvent interactions to be examined separately. No symmetry breaking was found in nonpolar solvents irrespective of their refractive index, indicating that differences in dispersion inte...