water contamination due to the wide variety of pesticides used in agriculture is a global environmental pollution problem. in order to reach at sub-î¼gl-1 levels of detection, an efficient extraction technique is required. a simple, fast and economical method, dispersive liquid-liquid micro extraction (dllme), followed by gas chromatography-mass spectrometry was assessed for determining endosul...

a very simple, rapid and sensitive dispersive liquid-liquid microextraction (dllme) followed by gas chromatography and flame ionization detection (gc-fid) was developed for the determination of phenol and carvacrol in honey samples. a mixture of 100 µl dichloromethane (extraction solvent) and 0.5 ml acetonitrile (disperser solvent) was rapidly injected into sample solution. thereby a cloudy sol...

an efficient dispersive liquid-liquid microextraction using tetraalkylammonium bromide coated silver nanoparticles (dllme-agnps) prepared in chloroform has been successfully applied as electrostatic affinity probes to the microextraction and preconcentration of terazosin prior to spectrofluorimetry analysis. this technique is based on a ternary system of solvents, where appropriate amount of mi...

a second virial coefficient correlation suitable for two different temperatures ranges, (t*)-2£180 and (t*)-2>180, where t* is rt/dhvap is presented. the equation of state can be calculated for different, complicated non-polar, and slightly polar liquid mixtures at any temperature over the range from ttp to tc and up to high pressures. the latent heat of vaporization and density at the triple p...

recently, 6-(2-naphthyl)-2, 3-dihydro-as-triazine-3-thione (ndtt) was synthesized in laboratory and used successfully for the spectrophotometric determination of nanogram levels of cu2+ in aqueous solution. this reagent forms a specific red complex with cu2+ ions after the extraction by chloroform at alkaline ph. the absorption of the complex in the uv region (313 nm) is about 8 times as strong...

a simple and rapid microextraction procedure based on dispersive liquid-liquid microextraction (dllme) was developed for determination and speciation of trace amounts of chromium (cr) by flame atomic absorption spectrometry (faas). in the proposed approach, chloroform and methanol were used as extraction and dispersive solvents. a new schiff's base ligand, bis(2-methoxy benzaldehyde) ethylene d...

In this study, liquid-liquid extraction process in a Kuhni extraction column was modeled and simulated. A non-equilibrium dynamic model was developed for modeling liquid-liquid extraction processes based on a rate-based model. The model equations are inclusive of partial and ordinary differential equations which were discretized in column height direction. The population balance model was used ...

a sensitive, selective and effective ionic liquid-based single drop microextraction technique was developed by using ionic liquid, 1-hexyl-3-methylimidazolium hexafluorophosphate, c6mimpf6, coupled with electrothermal atomic absorption spectrometry (etaas) for the determination of copper and silver in environmental samples. dithizone was used as chelating agent. several factors that influence t...