In this work, we develop a correlative model based on the surface tension data in order to calculate thermodynamic parameters, such as interaction energy between components (Uij), activity coefficients and etc. In the new approach, by using Li et al. (LWW) model, a three-parameter surface tension equation is derived for liquid mixtures. The surface tension data of 54 aqueous and 73 non-aqueous ...

The specific rates of solvolysis of isobutyl chloroformate (1) are reported at 40.0 °C and those for isobutyl chlorothioformate (2) are reported at 25.0 °C, in a variety of pure and binary aqueous organic mixtures with wide ranging nucleophilicity and ionizing power. For 1, we also report the first-order rate constants determined at different temperatures in pure ethanol (EtOH), methanol (MeOH)...

the srk two-parameter cubic equation of state has been used for the calculation of the equilibrium constant using the liquid and vapor fugacity coefficients for three binary mixtures. dew and bubble points have been determined using the equilibrium constants and the phase envelope has been plotted showing dearly that retrograde condenstaion occurs. the following percent deviations have been obt...

In this paper, the vapor-liquid equilibrium (VLE) properties of polar and nonpolar fluids are modeled by the use of a statistically-based equation of state (EOS). The equation of state used in this work is that of Ihm-Song-Mason (ISM) EOS. An alternative approach is to revise the isothermal integration on liquid. In this respect, a temperature-dependent revision factor b (T) is introduced to th...

a specific polymerase chain reaction (pcr) method was applied for identification of bovine (bos taurus), ovine (ovis aries) and caprine (capra hircus) pure and binary mixtures of raw and heat-processed meats. these meats are used in food industry products and/or for direct consumption of consumers. the mitochondrial dna was amplified as a template in a pcr reaction by use of specific primers re...

A specific polymerase chain reaction (PCR) method was applied for identification of bovine (Bos taurus), ovine (Ovis aries) and caprine (Capra hircus) pure and binary mixtures of raw and heat-processed meats. These meats are used in food industry products and/or for direct consumption of consumers. The mitochondrial DNA was amplified as a template in a PCR reaction by use of specific primers re...

in this study, the densities, excess molar volumes and partial molar volumes of four binary systems containing n,n-dimethyl acetamide (dmac) with 1-alkanols (1-butanol up to 1-heptanol) are measured at 298.15 k. the results showed both constructive and expansive excess volumetric behavior for studying binary mixtures. deviation values of heavy alcohol have more positive and less negative excess...

Abstract Background Plant secondary metabolites or mixtures in extracts essential oils are well known to enhance the activity binary mixtures. The present study is first report that thymol synergistically additively enhances of P. ribesioides and isolated compounds against S. exigua larvae at sublethal doses. Results Thymol was synergistic when mixed with hexane extract; however, if extract lev...

experimental results of dielectric investigations for binary mixtures of 2, 3-butanediol, 2, 3-bd, in2-ethyl-1-hexanol, 2eh, were reported for various mole fractions and temperatures (298.2-308.2) kand they were used to calculate dielectric parameters such as kirkwood correlation factor, excesspermittivity and bruggeman parameter. these parameters were used to carry out temperaturedependent die...