A reagent-free electrochemical chloride sensor for mineral water was investigated with a silver electrode particularly embracing the oxygen reduction reaction to active surface and avoid need mechanical polishing.

Various kinds of biosensors were developed for the environmental control. Microbial sensor consisting immobilized yeasts and oxygen probe has been applied to estimation of 5-day BOD. The response time of BOD sensor was less than 20 mm and the minimum measurable BOD was 3 mg l-. Amperometric microbial sensor for ammonia was constructed with immobilized nitrifying bacteria and an oxyger probe. Th...

The electrochemical oxidation of 2,4-toluene diisocyanate (2,4-TDI) in an ionic liquid (IL) has been systematically characterized to determine plausible electrochemical and chemical reaction mechanisms and to define the optimal detection methods for such a highly significant analyte. It has been found that the use of an IL as the electrolyte allows the oxidation of 2,4-TDI to occur at a less po...

The participation of cations in redox reactions of manganese oxides provides an opportunity for development of chemical sensors for non-electroactive ions. A sensor based on a nanostructured hollandite-type manganese oxide was investigated for voltammetric detection of potassium ions. The detection is based on the measurement of anodic current generated by oxidation of Mn(III) to Mn(IV) at the ...

This paper presents a framework for the optimal design of experiments for medical sensors calibration. A new software program, G-optimal, is developed to demonstrate the optimal design of experiment. This program has been used to find G-optimal design for amperometric enzyme glucose sensor, silicon capacitive absolute pressure sensors and electrochemical oxygen and carbon dioxide partial pressu...

The preparation of a cholesterol amperometric biosensor using a platinized Pt electrode as a support for the electropolymerization of a polypyrrole film, in which cholesterol oxidase and ferrocene monocarboxylic acid (electron-transfer mediator) were co-entrapped, is described. All the biosensor preparation steps (platinization and electropolymerization) and the cholesterol determination take p...

A lactate oxidase-based amperometric biosensor is designed for lactate determination. Two methods of lactate oxidase immobilization on the surface of commercial SensLab platinum printing electrodes are compared. The sensor with lactate oxidase immobilized by physical adsorption in Resydrol polymer is shown to have both narrower dynamic range (0.004– 0.5 mМ lactate) and higher sensitivity (320 n...

A new, improved sensor for the electrocatalytic determination of ascorbate has been developed that has both a low applied operating potential and a low detection limit. The sensor was constructed by depositing copper hexacyanoferrate film either electrochemically or chemically onto carbon film electrode, and it was then characterised by cyclic voltammetry and electrochemical impedance spectrosc...

The heat equation posed on the half-line may be used as a simple mathematical model describing the operation of an amperometric ion sensor. These sensors represent the next generation of sensors that are in routine use today. Such sensors may be used to measure ion concentrations in the laboratory, for clinical analysis, environmental monitoring, process and quality control, biomedical analysis...

A portable electrochemical sensor has been developed for determination of tricresyl phosphate (TCP) in gas phase. An alkaline catalyst column was used in an automatic TCP sampling system where gasified TCP was hydrolysed to cresol, making it electrochemically detectable. Hydrolysates were then detected in the flow injection analysis (FIA). Amperometric measurements were performed utilizing the ...