Layered nanoscale amorphous solid films of methanol and ethanol undergo complete intermixing prior to the onset of measurable desorption at 120 K. This intermixing precedes and inhibits crystallization. Subsequent desorption of the film is described quantitatively by a kinetic model describing evaporation from a continuously mixed ideal binary liquid solution. This occurs at temperatures below ...

Articles you may be interested in Asymmetrical degradation behaviors in amorphous InGaZnO thin-film transistors under various gate and drain bias stresses Investigation on the negative bias illumination stress-induced instability of amorphous indium-tin-zinc-oxide thin film transistors Appl. Temperature dependence of negative bias under illumination stress and recovery in amorphous indium galli...

The high-frequency reorientation dynamics of O–H bonds is investigated in various amorphous ices including eHDA (expanded high density amorphous ice), LDA-II (low density amorphous ice II) and HGW (hyperquenched glassy water) using H-NMR spin–lattice relaxation as a local probe. Both low density forms, HGW and LDA-II, show similar spin–lattice relaxation but differ in the thermal stability with...

Microstructure of a rapidly solidified Al-4V-2Fe alloy has been examined in detail by means of transmission electron microscopy and atom probe field ion microscopy. It is composed of a mixture of α-Al and amorphous phases. α-Al grains are relatively large (400 nm), but nanoscale domains of amorphous phase are trapped in the fcc grains. The interface between the α-Al and amorphous phases are ver...

Introduction An understanding of the crystallization kinetics of magnetic amorphous alloys is of scientific interest for two important reasons. First, for an alloy that exhibits excellent magnetic properties in its amorphous phase, the crystallization kinetics represent the limit at which these properties begin to deteriorate. Therefore, thermal stability determines the magnetic stability of th...

Topological insulators (TIs) are exotic materials which have topologically protected states on the surface due to strong spin-orbit coupling. However, a lack of ordered growth of TI thin films on amorphous dielectrics and/or insulators presents a challenge for applications of TI-junctions. We report the growth of topological insulator Bi2Se3 thin films on amorphous SiO2 by molecular beam epitax...

Recent studies of amorphous solid materials have revealed the possibility that more than one distinct amorphous phase may be formed from the same substance. In analogy with the phenomenon of crystalline polymorphism, this behavior has been termed “amorphous polymorphism”. We review the experimental manifestation of amorphous polymorphism, especially in tetrahedrally coordinated materials such a...

Among numerous active electrode materials, nickel hydroxide is a promising electrode in electrochemical capacitors. Nickel hydroxide research has thus far focused on the crystalline rather than the amorphous phase, despite the impressive electrochemical properties of the latter, which includes an improved electrochemical efficiency due to disorder. Here we demonstrate high-performance electroch...

  Objective: Amorphous calcium phosphate (ACP) is a reactive solution capable of releasing calcium and phosphate ions, conversion to apatite and remineralization of mineral tooth structure. This study reviews ACP structure, its properties and its applications in dentistry.   Methods: In this review study, keywords including “amorphous calcium phosphate”, “mineralization”, “hydroxyapatite”, “cas...

Crystallization kinetics of Fe52Cr18Mo7B16C4Nb3 alloy was evaluated using X-ray diffraction, differential scanning calorimetric (DSC) tests and TEM observations in this research work. In effect, crystallization and growth mechanisms were investigated using DSC tests in four different heating rates (10, 20, 30, 40 K/min) and kinetic models (i.e. Kissinger- Starink, Ozawa, and Matusita methods). ...