A PVC membrane Fe(III) ion selective electrode has been constructed using a new macrocyclic asmembrane carrier.The electrode exhibits a good potentiometric response for Fe(III) over a wideconcentration range 1.0×10-4 to 1.0×10-1M with a slope 19.4±0.5 mV/decade a and a working pHrange of 6.5-9.0. It has a fast response time ≤30s.The best performance was observed with themembrance having the 30....

A PVC ion-selective membrane electrode based on Cd-tetraphenyl porphyrine as a carrier was prepared fordetermination of MnO4- ion. This electrode revealed good selectivity toward permanganate ion over a widevariety of anions. Effects of some experimental parameters such as nature of the plasticizer, the amounts ofcarrier and additive, and concentration of the internal solution on the potential ...

in this work, the results concerning to the mean activity coefficient measurements for nacl in the (glycerol + water) system using the potentiometric method are reported. the potentiometric measurements were performed on the galvanic cells without liquid junction of the type: ag|agcl|nacl (m), glycerol (wt%), h2o (1 - wt)%|na-ise, in various mixed solvent systems containing 0, 5, 10, 20 and 30 ...

Sol-gel and polymeric membrane electrodes, based on thiacalix[4]arene as a neutral carrier, weresuccessfully developed for the detection of VO2+ in aqueous solutions. The sol-gel and PVCmembrane electrodes exhibited linear response with Nernstian slopes of 29.3 and 28.4 mV perdecade, respectively, within the vanadyl ion concentration ranges from 1.0 × 10-6 to 1.0 × 10-1mol dm-3 and from 1.0 × 1...

fabrication of a cysteamine (ca) self-assembled monolayer (sam) modified gold electrode insitufunctionalized with l-lysine (lys) is presented and described. the fabricated electrode was used forhighly selective and sensitive accumulation and the determination of copper ions (cu2+) in a nanomolarconcentration. techniques like cyclic voltammetry (cv) and electrochemical impedance spectroscopy (ei...

Metformin in its protonated form as metformin hydrochloride is used worldwide an advanced antidiabetic drug for type 2 diabetes. Hyperinsulinemia and insulin resistance of cells are the main causes this disease. For patients with diabetes, (MET) works by improving cell sensitivity to insulin.
 It has been shown that methyl orange (MO) forms ionic associate can be isolated solid suitable cr...