نتایج جستجو برای: acidic medium electrochemical measurements

تعداد نتایج: 671987  

Journal: :Faraday discussions 2014
Elzbieta Frackowiak Mikolaj Meller Jakub Menzel Dominika Gastol Krzysztof Fic

This paper reports the electrochemical behaviour of supercapacitor carbon electrodes operating in different aqueous solutions modified by various redox-active species (hydroxybenzenes, bromine derivatives and iodide). Three dihydroxybenzenes with varying stereochemistry, i.e., -OH substitution, have been considered as electrolyte additives (0.38 mol L(-1)) in acidic, alkaline and neutral soluti...

پایان نامه :وزارت علوم، تحقیقات و فناوری - دانشگاه رازی - دانشکده علوم 1390

abstract ion selective electrodes (ises) are electrochemical sensors that respond selectivity to the activity of ionic species. an ion-selective electrode is an electrochemical device that uses a thin selective membrane or film as the recognition element, and is an electrochemical half-cell equivalent to other half-cells of the zeroth (inert metal in a redox electrolyte). in common methods o...

ژورنال: :international journal of new chemistry 0

in this study, the electrochemical mechanism of catechol in presence and absence of nitrite ion, is investigated in phosphate buffer medium (ph=7) using platinum electrode through cyclic voltammetry method in various scan rates. electrochemical oxidation of catechol showed how quinone has changed to o-benzoquinone and also how o-benzoquinone has reacted with nitrite ion and potential scan rate ...

2003
CHARLES W. CARR

In several recent publications 1-6 we have shown experimentally that the acidic groups present in collodion are the primary cause of its electrochemical activity in solutions of strong inorganic electrolytes. The surface concentration of these acidic dissociable groups is assumed to determine the degree of electrochemical activity of any given collodion sample. The abundance of these groups var...

2012
Farzin Arjmand Annemie Adriaens

The effects of pH and chloride concentration on the electrochemical corrosion of copper in aqueous sodium chloride (NaCl) media were studied at the micro scale using a microcapillary droplet cell and at the macro scale using a conventional large scale cell. Using an experimental design strategy, electrochemical response surface models of copper versus pH and NaCl concentration were constructed ...

Journal: :iranian journal of chemistry and chemical engineering 0

to improve the corrosion protection of copper metal, 0.01m concentration of 1h-1,2,4-triazole-3-thiol (tat) was incorporated into the hybrid sol-gel monolayers containing 3-glycidoxypropyltrimethoxysilane (gptms) and tetraethoxysilane (teos). it was further subjected to hydrolysis and condensation reaction to form a sol-gel matrix. the tat-doped hybrid sol-gel coating was applied over the coppe...

2013
Bo Young Jeon Il Lae Jung Doo Hyun Park

In this research, metabolic fixation of CO2 by growing cells of C. acetobutylicum cultivated with electrochemical reducing power was tested on the basis of the metabolites production and genes expression. In cyclic voltammetry, electrochemical oxidation and reduction reaction of neutral red (NR) immobilized in intact cells of C. acetobutylicum was stationarily repeated like the soluble one in t...

Journal: :Journal of the Japan Institute of Metals and Materials 1989

A. Islamnezhad M. Arvand M.A. Zanjanchi

12-molybdophosphoric acid (PMo12) was encaged into HMOR zeolite by “ship in a bottle”method in aqueous phase which is strongly retained and not easily leached from the host channels.The solid was characterized by XRD prior to using it for the electrode preparation. This compoundwas incorporated with a carbon paste electrode for cyclic voltammetric measurements. PMo12immobilized on the support u...

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