The title compound, C(13)H(12)ClNO(4), is approximately planar, with a dihedral angle of 8.23 (4)° between the mean plane of the amino-methyl-ene unit and the planar part of the dioxane ring. The dioxane ring has a half-boat conformation, in which the C atom between the dioxane O atoms is -0.464 (8) Å out of the plane of the other five atoms. In the mol-ecule there is an intra-molecular N-H⋯O h...

The title compound, [Na(3)(C(14)H(14)N(3)O(3)S)(3)(C(4)H(8)O(2))(3)](n), is a polynuclear complex which includes, in the monomeric unit, three units of Na(I)-4'-dimethyl-amino-azobenzene-4-sulfonate [known as methyl orange (MO)] and three molecules of dioxane (C(4)H(8)O(2)). These constitute three kinds of Na(I) centres, two of which are seven-coordinate while the third is five-coordinate. One ...

(DAF)Pd(OAc)2 (DAF = 4,5-diazafluorenone) catalyzes aerobic intramolecular aryl C-H amination with N-benzenesulfonyl-2-aminobiphenyl in dioxane to afford the corresponding carbazole product. Mechanistic studies show that the reaction involves in situ generation of peroxide species from 1,4-dioxane and O2, and the reaction further benefits from the presence of glycolic acid, an oxidative decompo...

Small structural changes in organic molecules can have a large influence on solid-state crystal packing, and this often thwarts attempts to produce isostructural series of crystalline solids. For metal-organic frameworks and covalent organic frameworks, this has been addressed by using strong, directional intermolecular bonding to create families of isoreticular solids. Here, we show that an or...

The low-frequency Raman spectra of dioxane aqueous solutions have been analyzed from a dynamical aspect of water structure. The reduced Raman spectra x9( n̄) of the dioxane aqueous solutions are well explained by a superposition of three characteristic modes of water and one Gaussian mode ~;60 cm! of dioxane. The concentration dependence of x9( n̄) spectra shows that the 190 cm mode of water disa...

Six-membered ring cyclohexane derivatives with 2 oxygen (1,4-dioxane or p-dioxane) and 3 (1,3,5-trioxane) atoms have been used as organic molecules in the synthesis of zeolites omega (MAZ framework type) ECR-1 (EON type). Both yield zeolite at moderate temperatures a composition aluminum distribution similar to those obtained more standard organics such tetramethylammonium cation. If preparatio...

Global concern over the carcinogenic potential of 1,4-dioxane and several nitrosamines has resulted in increased interest in the development of more efficient testing methods for these contaminants in drinking waters. In the U.S., the current methodologies recommended for the analysis of 1,4-dioxane and nitrosamines in drinking waters are Environmental Protection Agency (EPA) Methods 522 and 52...

In the title compound, C(13)H(12)BrNO(4), the dihedral angles between the amino-methyl-ene group and the dioxane ring and between the benzyl ring and the amino-methyl-ene unit are 7.96 (4) and 12.15 (4)°, respectively. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.460 (8) Å out of the plane through the remaining ring atoms. An intra-m...

The asymmetric unit of the title compound,, C(4)H(4)N(2)O(5)·0.5C(4)H(8)O(2), contains one molecule of 5,5-dihydroxybarbituric acid with a nearly planar barbiturate ring and half a molecule of 1,4-dioxane. The geometry of the centrosymmetric dioxane molecule is close to an ideal chair conformation. The crystal structure exhibits a complex three-dimensional hydrogen-bonded network. Barbiturate m...

In the title compound, C(13)H(12)N(2)O(6), the dihedral angle between the benzene ring and the amino-methyl-ene unit is 5.42 (16)°, while the angle between the amino-methyl-ene unit and the dioxane ring is 3.06 (43)°. The dioxane ring shows a half-boat conformation, in which the C atom between the dioxane ring O atoms is 0.464 (10) Å out of the plane. An intra-molecular N-H⋯O hydrogen bond stab...