Phosphorus L-edge and oxygen K-edge X-ray PhotoEmission Electron Microscopy (XPEEM) have been used to characterize the chemical nature of the cation present in tribochemical films via comparison with model Fe and Zn compounds. The results are contrasted to the P L-edge, P K-edge and S K-edge XANES data. The findings suggest that antiwear pads containing long chain zinc polyphosphate glass are f...