Starting with metal dithiocarbamate complexes, we synthesize colloidal Cu(2)ZnSnS(4) (CZTS) nanocrystals with diameters ranging from 2 to 7 nm. Structural and Raman scattering data confirm that CZTS is obtained rather than other possible material phases. The optical absorption spectra of nanocrystals with diameters less than 3 nm show a shift to higher energy due to quantum confinement.

Cu2ZnSnS4 (CZTS) thin films were prepared by directly sputteringCu (In,Ga)Se2 quaternary target consisting of (Cu: 25%, Zn: 12.5%, Sn; 12.5%and S: 50%). The composition and structure of CZTS layers have beeninvestigated after annealing at 200 0C, 350 0C and 500 0C under vacuum. Theresults show that recrystallization of the CZTS thin film occurs and increasingthe grain size with a preferred orie...

The present work demonstrates a systematic approach for the synthesis of pure kesterite-phase Cu2ZnSnS4 (CZTS) nanocrystals with a uniform size distribution by a one-step, thioglycolic acid (TGA)-assisted hydrothermal route. The formation mechanism and the role of TGA in the formation of CZTS compound were thoroughly studied. It has been found that TGA interacted with Cu(2+) to form Cu(+) at th...

In this article, ZnO and ZnO:Mn nanoparticles prepared by reverse micelle method. The various crystalline properties of these nanoparticles such as size, d-spacing, strain, stress, dislocation density and texture coefficient have been calculated with the help of XRD spectrum. The XRD results indicated that the synthesized ZnO and ZnO:Mn nanoparticles have a pure wurtzite (hexagonal phase) struc...

Facile low-temperature chemical route for the synthesis of ZnO nanoparticles is reported in this paper. Morphologically uniform and spherical shape with an average particle size of 8.8 nm and wurtzite phase with the crystalline structure of as-synthesized ZnO nanoparticles were confirmed by X-Ray Diffraction (XRD), Scanning Electron Microscopy (SEM) and Transmissi...

As is well documented, platinum nanoparticles, promising for catalysts for fuel cells, exhibit better catalytic activities, when alloyed with Zn. Pre-existing syntheses of Pt-Zn alloy catalysts are composed of a number of complex steps. In this study, we have demonstrated that nanoparticles of Pt-Zn alloys are simply generated by electron-beam irradiation in a transmission electron microscope o...

In this article, ZnO and ZnO:Mn nanoparticles prepared by reverse micelle method. The various crystalline properties of these nanoparticles such as size, d-spacing, strain, stress, dislocation density and texture coefficient have been calculated with the help of XRD spectrum. The XRD results indicated that the synthesized ZnO and ZnO:Mn nanoparticles have a pure wurtzite (hexagonal phase) struc...

In this article, synthesis procedures of preparation of copper zinc tin sulpho-selenide (CZTS x Se1-x ) alloy nanocrystals and the data acquired for the material characterization are presented. This data article is related to the research article doi: http://dx.doi.org/10.1016/j.solmat.2016.06.030 (Jadhav et al., 2016) [1]. FTIR data have been presented which helped in confirmation of adsorptio...

Pure-sulphide Cu2ZnSnS4 (CZTS) thin film solar cells were prepared by a low-cost, non-toxic and high-throughput method based on the thermal decomposition and reaction of sol-gel precursor solution, followed by a high temperature sulfurization process in sulphur atmosphere, which usually gave rise to the unexpected Cu-poor and Zn-rich phase after sulfurization. In order to remove the formation o...

Porous copper zinc tin sulfide (CZTS) thin film was prepared via a solvothermal approach. Compared with conventional dye-sensitized solar cells (DSSCs), double junction photoelectrochemical cells using dye-sensitized n-type TiO(2) (DS-TiO(2)) as the photoanode and porous p-type CZTS film as the photocathode shows an increased short circuit current, external quantum efficiency and power conversi...