Results obtained by computer modeling and simulation using ab-initio and molecular dynamics techniques for elucidation of structural and catalytic properties of the PdCoMo trimetallic compound are reported; a comparison of these results with those obtained by sputtering deposition onto a nafion membrane to be used as catalyst for a 1KW PEM fuel cell is made. Structure was calculated by ab-initi...

The extended site-binding model, which explicitly separates intramolecular interactions (i.e., intermetallic and interligand) from the successive binding of metal ions to polytopic receptors, is used for unravelling the self-assembly of trimetallic double-stranded Cu(I) and triple-stranded Eu(III) helicates. A thorough analysis of the available stability constants systematically shows that nega...

In this paper, we report on the optimization of SnO2-based thin film gas sensor devices by mono-, bi- and trimetallic nanoparticles. Ag, AgRu, AgRuPd nanoparticles are sputter deposited CMOS-integrated SnO2-thin devices. The CMOS device is a worldwide unique chip containing an array eight microhotplates. response towards target CO was dramatically increased from 10% to more than 70% using

The reaction of Fe(C≡CC≡N)(dppe)Cp (1) with one-half equivalent of [trans-Fe(N≡CMe)2(dppx)2][BF4]2 (dppx = dppe ([2][BF4]2) or dppm ([3][BF4]2)) affords trimetallic [trans-Fe{N≡CC≡CFe(dppe)Cp}2(dppx)2][BF4]2 (dppx = dppe [4][BF4]2; dppx = dppm [5][BF4]2). Both [4][BF4]2 and [5][BF4]2 undergo three, one-electron oxidation processes, arising from sequential oxidation of the two terminal Fe(C≡CR)(...

The heteronuclear trimetallic d–f–d complex [Eu(btfa)3{(Ph)(Et3P)2Pt–CC–R–CC–Pt(Et3P)2(Ph)}] has been synthesized and characterized spectroscopically. displays both red green emissions in solution.

Reaction of [AuCl(PPh(3))] with the zwitterion S(2)CNC(4)H(8)NH(2) yields [(Ph(3)P)Au(S(2)CNC(4)H(8)NH(2))]BF(4). Treatment of this species with NEt(3) and CS(2) followed by [AuCl(PPh(3))] leads to [{(Ph(3)P)Au}(2)(S(2)CNC(4)H(8)NCS(2))], which can also be obtained directly from [AuCl(PPh(3))] and KS(2)CNC(4)H(8)NCS(2)K. A heterobimetallic variant, [(dppm)(2)Ru(S(2)CNC(4)H(8)NCS(2))Au(PPh(3))](...

Pd, Cu, and Zn trimetallic metal-organic framework electrocatalysts (PCZs) based on benzene-1,3,5-tricarboxylic were synthesized using a simple solvothermal synthesis. The as-synthesized PCZ catalysts exhibited as much 95% faradaic efficiency towards CO, with high current density, low onset potential, excellent long-term stability during the electrocatalytic reduction of CO2.