effect of water gas shift reaction (co+h2o=co2+h2) on wustite reduction has been investigated by a transient, non-isothermal mathematical model based on grain model. in this model, wustite porous pellet is reduced using syngas, namely a mixture of hydrogen, carbon monoxide, carbon dioxide and water vapor. for this purpose, governing equations containing continuity equation of species and energy...

soil is well known to support the transient or ongoing existence of kerathophilic fungi and potential sources of infection for humans and animals. fifty soil samples were collected from various areas of forests and farmyards at golestan province in the north part of iran to determine the prevalence of keratinophilic fungi and dominant species. a total of 357 fungal colonies including 13 genera ...

Extended Abstract Biological function involves a series of chemical reactions of biological molecules, and during these reactions, there are numerous spectrally silent dynamic events that cannot be monitored by absorption or emission spectroscopic techniques. Such spectrally silent dynamics include changes in conformation, intermolecular interactions (hydrogen bonding, hydrophobic interactions)...

detection and modification of the risk factors of stroke may be the most effective strategy for preventing its often irreversible consequences. a longitudinal prospective study was implemented to evaluate the effect of several risk factors on the course of cerebrovascular disease. the study groups were composed of 3s8 normal volunteers, and 308 patients with transient ischemic attacks. the two ...

Waterlogging reduces the yield of food crops. Tolerance to waterlogging could vary between and within species. This study aimed to quantify tolerance to soil waterlogging in two divergent genotypes of pea (Pisum sativum), two of lentil (Lens culinaris) and a grasspea (Lathyrus sativus) control at germination and during vegetative growth. Following germination, seeds were grown for 14 days in so...

Energy-dependent quenching of excitons in photosystem II of plants, or qE, has been positively correlated with the transient production of carotenoid radical cation species. Zeaxanthin was shown to be the donor species in the CP29 antenna complex. We report transient absorbance analyses of CP24 and CP26 complexes that bind lutein and zeaxanthin in the L1 and L2 domains, respectively. For CP24 c...

x-ray photoelectron and high resolution electron energy loss spectroscopic (xps-hreels) studies have shown that the adsorption of carbon dioxide at mg(100) surfaces at 80k is followed by a dissociative reaction leading to the formation of a metastable surface carbonate above 80k. the formation of a carbonate species is proposed to proceed through oxidation of c0 (g) by an active oxygen surface ...

We analyze the transient dynamics of simple models of keystone predation, in which a predator preferentially consumes the dominant of two (or more) competing prey species. We show that coexistence is unlikely in many systems characterized both by successful invasion of either prey species into the food web that lacks it and by a stable equilibrium with high densities of all species. Invasion of...

The step-by-step free energy (ΔG) profile of the sarcoplasmic reticulum CaATPase cycle during the transient state of simulated reactions was analyzed previously by Alonso and Hecht (1990). ΔG was negative at all the steps. Here we calculated the step-by-step activation energies (ΔG ) in the same model according the transition state theory. Transient species were introduced as chemical intermedi...

The carrier dynamics in dye-sensitized solar cells was investigated by using the transient grating, in addition to the transient absorption method and transient photocurrent method on the order of microseconds to seconds. The signals for the same sample were obtained under a short-circuit condition to compare the carrier dynamics via refractive index change with the transient photocurrent measu...