Spinodal decomposition in a near-critical binary fluid is examined for experimental scenarios which the liquid quenched abruptly by changing pressure and subsequent phase separation occurs with no heat flow from outside, i.e., adiabatically. Equations of motion system volume effective temperature are derived. It shown that this case nonequilibrium process well approximated as one constant entro...

This study deals with the fabrication of biodegradable porous materials from bacterial polyester, poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (P3HB3HHx), via thermally induced phase separation. P3HB3HHx monoliths with topological porous structure were prepared by dissolution of P3HB3HHx in dimethyl sulfoxide (DMSO) at 85 ̋C and subsequent quenching. The microstructure of the resulting P3HB3HH...

In this work, three different graphene-based materials, namely graphite oxide (GrO), thermally reduced graphite oxide (T-RGrO) and ascorbic acid multi-phase reduced graphene oxide (AMP-RGO), were synthesized and used to produce mixed matrix membranes (MMM) based on Matrimid®5218 for as separation. From the samples produced, a complete set of characterization was performed including XRD, FTIR, T...

A theory is presented for the intermembrane junction separation induced by the adhesion between two biomimetic membranes that contain two different types of anchored intermembrane junctions (receptor-ligand complexes). The analysis shows that several mechanisms contribute to the phase separation of the membrane junctions. These mechanisms include the following. (i) The elasticity of the membran...

Three-dimensional (3-D) scaffolds with intrinsic porous structures are desirable in various tissue regeneration applications. In this study, a unique method that combines thermally induced phase separation with a photocrosslinking process was developed for the fabrication of 3-D crosslinked polymer scaffolds with densely interconnected porous structures. Biodegradable poly(propylene fumarate)-c...

Highly porous poly(D,L-lactic-co-glycolic acid) (PLGA) scaffolds were fabricated by a thermally-induced phase-separation (TIPS) method to deliver plasmid DNA in a controlled manner. A variety of TIPS parameters directly affecting pore structures and their interconnectivities of the scaffold, such as polymer concentration, solvent/non-solvent ratio, quenching methods and annealing time, were sys...

Nano-fibrous scaffolds which could potentially mimic the architecture of extracellular matrix (ECM) have been considered a good candidate matrix for cell delivery in tissue engineering applications. In the present study, a semicrystalline diblock copolymer, poly(epsilon-caprolactone)-block-poly(L-lactide) (PCL-b-PLLA), was synthesized and utilized to fabricate nano-fibrous scaffolds via a therm...

Phase separation simulation study related to cellulose acetate-water-acetone has been done. Results show that porous asymmetric and symmetric membranes can be produced by changing the nonsolvent concentration or by the drying conditions without altering the polymer content using dry-casting process. Dry-casting process is the process in which complete evaporation of solvent and nonsolvent takes...