Despite the current interest in selenium chemistry [1—6], oxidations by selenium dioxide remained limited to only a few classes of compounds, mainly alkenes and carbonyl compounds, in addition to some special cases [7, 8]. Selenium dioxide is the cheapest and most convenient selenium reagent, and an extension of its applications to other types of com­ pounds is therefore of considerable interes...

Ru=O complexes have been demonstrated to be competent oxidants for oxidation of saturated hydrocarbons and epoxidat ion of alkenes . Photoexcitation of transdioxoosmium(V1) gives rise to super-oxidizing complexes having EO >2.2 V vs. n.h.e.. Some cationic RuZN and OsZN complexes are good model system for study of the mechanism of metalcatalysed oxidation of ammonia to nitrite and activation of ...

Ultrafine silicon quantum wires with high-quality Si/SiO2 heterointerfaces are successfully fabricated by utilizing anisotropic wet chemical etching and subsequent thermal oxidation. It is also found that the lateral dimensions of silicon quantum wires can be well controlled by selecting the temperature of the thermal oxidation process. The cross-sectional image from a scanning electron microsc...

We have investigated the role of aluminum oxide films as barriers to thermal oxidation of Co, Ni, Fe, Ni Fe , Mn, Ta, Cu 80 20 and Cr in air. The oxidation of the film is monitored by measuring the electrical resistance following a brief anneal in air. We find that 0.3 and 1 nm Al protect the underlying metal film against thermal oxidation in air at temperatures of a few hundred degrees above t...

Heavy metals (HMs) are common components of landfill leachates and piggery wastewater, which correspond with possible applications of the anaerobic ammonium oxidation (anammox). For this reason, the study of the fate and effect of HMs on the anammox process is of utmost importance. In this work, the effect of several HMs on the specific anammox activity (SAA) was studied. For this purpose, the ...

We report a method for manipulating feature sizes in Si-based grating structures by thermal oxidation, which allows the realization of fin width/period ratios not directly accessible by laser interference lithography. Taking advantage of the expansion in volume associated with the thermal oxidation of Si, grating structures with very high fin width/period ratios of the order of 0.96 were obtain...

In the study, Reactive Black 5 (RB5) was removed from synthetic wastewater using Fenton's oxidation (FO) process. Batch experiments were conducted on the samples containing 50, 250 and 500 mg/L of RB5. The study was performed in the systematic optimum value of H2O2 and FeSO4 concentrations, pH and temperature. Optimum pH and temperature for 250 mg/L RB-5 were observed at 3.0 and 40°C respective...

In this work we investigated the diffusion and clustering of supersaturated substitutional carbon 200nm thick SiGeC layers buried under a silicon cap layer of 40nm. The samples were annealed in inert (N2) or oxidizing (O2) ambient at 850°C for times ranging from 2 to 10 hours. The silicon self-interstitial (I) flux coming from the surface under oxidation enhances the C diffusion with respect to...

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