iodine as a trace micronutrient has important role in body physiology and its sufficient intake is essential for synthesize and secrete adequate amounts of thyroid gland hormones which influenced all periods of human life including fetal, childhood and adolescence. the aim of this study was to evaluate iodine concentration in marketed edible salt samples in lorestan province, comparing with exi...

The use of anions of 6,6'-bis(1H-tetrazol-5-yl)-2,2'-bipyridine (H2btzbp) as chelating ligands in preparing a coordination polymer is described. The synthesis, X-ray crystal structure and magnetic properties of a new Co(II) coordination polymer, [Co(btzbp)]n (1), are reported. The in situ [2 + 3] cycloaddition reaction of 6,6'-dicyano-2,2'-bipyridine with sodium azide in the presence of Co(ClO4...

As a continuation of the study on using the tetrazolate ligands to construct coordination polymers, two isomorphous 3D coordination polymers built on Δ-chain topological rod-shaped SBUs have been synthesized with formulae [M(2)(μ(3)-OH)L(1)L(2)](n) (5-amino-1H-tetrazole (HL(1)), 2,3-pyrazinedicarboxylic acid (H(2)L(2)) and different 3d spin carriers (M = Mn(II), 1 and Co(II), 2)). The SBU consi...

Three novel tetrazole-based frustrated magnets, namely, Co3(OH)2(3-ptz)2(SO4)(H2O)4 (1), Co2(OH)(tzba)(H2O)4 (2) and [Co(OH)(tta)] (3) (3-ptz = 5-(3-pyridyl) tetrazole, H2tzba = 4-(1H-tetrazol-5-yl) benzoic acid, Htta = 1H-tetrazole) were hydrothermal synthesized and magnetically characterized. Compound 1 is a 2D (4,4) layered structure assembled by sulfate capped triangular [Co3(μ3-OH)(μ3-SO4)...

thimerosal, which is approximately 50% mercury by weight is a preservative widely used in vaccines since the 1930’s. it meets the requirements for a preservative as set forth by pharmacopeia challenge test and has been shown to be effective against a broad spectrum of pathogens. in july 1999, the public health service agencies and vaccine manufacturers agreed that thimerosal should be reduced o...

protein aggregation and precipitation is associated with many debilitating diseases including alzheimer's, parkinson's, and light-chain amyloidosis. β-casein, a member of the casein family, has been demonstrated to exhibit chaperone-like activity to protect protein form aggregation. hofmeister salts (lyotropice series) are a class of ions which have an effect on the solubility and also the stab...

Density functional computations were performed on two tetracoordinated Ni(II) complexes as high nitrogen content energetic materials (1: dinickel bishydrazine ter[(1H-Tetrazol-3-yl)methan-3yl]-1H-tetrazole and 2: dinickel tetraazide ter[(1H-Tetrazol-3-yl)methan-3yl]-1H-tetrazolate). The geometrical structures, relative stabilities and sensitivities, and thermodynamic properties of the complexes...

We report on the exploitation of a new tetrazole-substituted 1,10-phenanthroline and a 2,2'-bipyridine (bpy) ancillary ligand modified with an electron-donating group in cationic ruthenium complexes. This complex, placed in between two electrodes without any polymer, demonstrates high efficiency near-infrared (NIR) electroluminescence (EL). The comparison between bpy and its methyl-substituted ...