Chemical vapor deposition (CVD) precursor chemicals are held to some of the highest purity levels in industry. Many metal reagents form stable, unbreakable adducts with the coordinating solvents that are necessary for solvating highly polar reagents. These adducts are undesirable and must be removed prior to usage. Herein we describe a mechanochemical approach to the synthesis of bis(n-propylte...

INTRODUCTION The conversion of synthesis gas to methanol is practiced commercially in gas phase fixed bed reactors over a Cu/Zn/Al,O1 catalyst. However, because of the highly exothermic nature of the synthesis reactions, heat dissipation has been a bottleneck in the reactor design and process configuration. Moreover, coalderived synthesis gas, having a low H,/CO ratio, is not suitable for use i...

Biological hydrogen production by anaerobic bacterium, Rhodospirillum rubrum was studied in batch and continuous bioreactors using synthesis gas (CO) as substrate. The systems were operated at ambient temperature and pressure. Correlations available in the literature were used to estimate the gas-liquid mass transfer coefficients (KLa) in batch reactor. Based on experimental results for the con...

The enactment of strict laws on reducing pollution and controlling combustion has given rise to the necessity of considering a new approach to energy supply in the future. One such approach is the use of hydrogen as an alternative to fossil fuels. Hydrogen and synthesis gas are typically produced through the partial oxidation of methane in porous media. This process was theoretically simula...

In the present study, the Differential Evolution (DE), an evolutionary computation technique, is applied to the optimal design of an auto-thermal ammonia synthesis reactor. This paper also presents the new concept of “Nested DE” (DE is also used to find out the best combination of key parameters of DE itself). The main objective in the optimal design of an autothermal ammonia synthesis reactor ...

Synthetic photochemistry carried out in classic batch reactors has, for over half a century, proved to be a powerful but under-utilised technique in general organic synthesis. Recent developments in flow photochemistry have the potential to allow this technique to be applied in a more mainstream setting. This review highlights the use of flow reactors in organic photochemistry, allowing a compa...

A new simple procedure for microwave-assisted organic synthesis under continuous flow processing has been developed for use in a monomodal microwave synthesizer with direct temperature control using the instrument's in-built IR sensor. This design makes optimum use of the standing wave cavity to improve the energy efficiency of microwave-assisted flow reactions.

This project deals with the problem at the core of chemical processes, that of creating a structure for the reaction-separation-recycle system. New methods have been developed for the synthesis of such structures capable of screening a wide range of options and taking account of all of the trade-offs simultaneously. For the first time these methods are capable of fully taking into account the i...

the nanoparticles of ti and tio2 have attracted extensive research interest because of their diverse applications in, for instance, catalysis, energy conversion, pigment and cosmetic manufacturing and biomedical engineering. through this project, a one-step bulk synthesis method of electromagnetic levitational gas condensation (elgc) was utilized for the synthesis of monodispersed and crystalli...