Recent studies of supported vanadium oxide catalysts have revealed that the vanadium oxide component is present as a twodimensional metal oxide overlayer on oxide supports (i.e., A1203, TiO2) (1-9). These surface vanadium oxide species are generally more selective and active than bulk, crystalline V205 for the partial oxidation of hydrocarbons (3, 5, 10, 11). The molecular structures of these s...

BACKGROUND Some studies have linked colorectal cancer to metal exposure. AIMS Our objective was to evaluate the element distribution in colorectal adenocarcinoma biopsies, adjacent non-tumour tissues, and healthy controls. METHODS The study is a case-control study which compared the element distribution in colon biopsies from two groups of patients: with colorectal cancer (2 types of sample...

vanadium supported on highly ordered nanoporous silica (vox-lus-1) was synthesized and characterized by xrd, nitrogen adsorption‑desorption isotherms and uv-visible spectrophotometer. direct oxidation of benzene to phenol in liquid phase by h2o2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). the maximum yield (25%) and selectivity (73%) of the ph...

A wide range of minerals is essential for human health. The recommended dietary allowances (RDAs) serve as guidelines for daily intakes of nutrients that population groups in the United States should have in their diets. Dietary Reference Intakes (DRIs) have been established for the following essential minerals: calcium, phosphorus, and magnesium. In addition, DRIs have been set for other trace...

The interaction of vanadium oxide and niobium oxide with A1203 and TiO2 supports is examined with Raman spectroscopy. The Raman spectra of the supported metal oxides reveal that the strong interaction of the metal oxides with AI203 and TiO2 supports results in the formation of two-dimensional surface metal oxide overlayers. The surface vanadium oxide overlayers are unstable to high calcination ...

The partial oxidation of methanol to formaldehyde was studied over highly dispersed vanadia supported on mesoporous silica SBA-15 (VOx/SBA-15). VOx/SBA-15 catalysts were prepared by a novel grafting/ion-exchange method and characterized using UV-VISand Raman spectroscopy. The resulting surface vanadium oxide species (0 – 2.3 V/nm), grafted on the inner pores of the SBA-15 silica matrix, consist...

Alumina-supported vanadium particles were prepared under ultrahigh vacuum (UHV) conditions and characterized with respect to their structural and CO adsorption properties. As supporting oxide, we used a thin, well-ordered alumina film grown on NiAl(110). This allows the application of scanning tunneling microscopy (STM), infrared reflection-absorption spectroscopy (IRAS), and X-ray photoelectro...